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Neutral atoms of the chemical elements have the same term symbol for each column in the s-block and p-block elements, but differ in d-block and f-block elements where the ground-state electron configuration changes within a column, where exceptions to Hund's rules occur. Ground state term symbols for the chemical elements are given below.
This notation is used to specify electron configurations and to create the term symbol for the electron states in a multi-electron atom. When writing a term symbol, the above scheme for a single electron's orbital quantum number is applied to the total orbital angular momentum associated to an electron state. [4]
We need to consider only the outer 3p 2 electrons, for which it can be shown (see term symbols) that the possible terms allowed by the Pauli exclusion principle are 1 D , 3 P , and 1 S. Hund's first rule now states that the ground state term is 3 P, which has S = 1. The superscript 3 is the value of the multiplicity = 2S + 1 = 3.
In molecular physics, the molecular term symbol is a shorthand expression of the group representation and angular momenta that characterize the state of a molecule, i.e. its electronic quantum state which is an eigenstate of the electronic molecular Hamiltonian. It is the equivalent of the term symbol for the atomic case.
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The x-axis of a Tanabe–Sugano diagram is expressed in terms of the ligand field splitting parameter, Δ, or Dq (for "differential of quanta" [5] [6]), divided by the Racah parameter B. The y-axis is in terms of energy, E, also scaled by B. Three Racah parameters exist, A, B, and C, which describe various aspects of interelectronic repulsion.
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