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A stirred BZ reaction mixture showing changes in color over time. The discovery of the phenomenon is credited to Boris Belousov.In 1951, while trying to find the non-organic analog to the Krebs cycle, he noted that in a mix of potassium bromate, cerium(IV) sulfate, malonic acid, and citric acid in dilute sulfuric acid, the ratio of concentration of the cerium(IV) and cerium(III) ions ...
A Belousov–Zhabotinsky reaction is one of several oscillating chemical systems, whose common element is the inclusion of bromine and an acid. An essential aspect of the BZ reaction is its so-called "excitability"—under the influence of stimuli, patterns develop in what would otherwise be a perfectly quiescent medium.
A chemical computer, also called a reaction-diffusion computer, Belousov–Zhabotinsky (BZ) computer, or gooware computer, is an unconventional computer based on a semi-solid chemical "soup" where data are represented by varying concentrations of chemicals. [1] The computations are performed by naturally occurring chemical reactions.
Boris Pavlovich Belousov (Russian: Бори́с Па́влович Белоу́сов; 19 February 1893 – 12 June 1970) was a Soviet chemist and biophysicist who discovered the Belousov–Zhabotinsky reaction (BZ reaction) in the early 1950s. His work initiated the field of modern nonlinear chemical dynamics. [1]
The Oregonator is a theoretical model for a type of autocatalytic reaction. The Oregonator is the simplest realistic model of the chemical dynamics of the oscillatory Belousov–Zhabotinsky reaction. [1] It was created by Richard Field and Richard M. Noyes at the University of Oregon. [2] It is a portmanteau of Oregon and oscillator.
Anatol Markovich Zhabotinsky (Анато́лий Ма́ркович Жаботи́нский) (January 17, 1938 – September 16, 2008) was a Soviet biophysicist who created a theory of the chemical clock known as Belousov–Zhabotinsky reaction in the 1960s and published a comprehensive body of experimental data on chemical wave propagation and pattern formation in nonuniform media.
The active ingredient is the [Fe(o-phen) 3] 2+ ion, which is a chromophore that can be oxidized to the ferric derivative [Fe(o-phen) 3] 3+. The potential for this redox change is +1.06 volts in 1 M H 2 SO 4. It is a popular redox indicator for visualizing oscillatory Belousov–Zhabotinsky reactions.
Chemical clock reactions such as the Belousov–Zhabotinsky reaction demonstrate that component concentrations can oscillate for a long time before finally attaining the equilibrium. Free energy In general terms, the free energy change (ΔG) of a reaction determines whether a chemical change will take place, but kinetics describes how fast the ...