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This electrochemical theory of valence found its most elaborate expression in the work of Richard Abegg in 1904, [39] but Lewis’ version of this theory was the only one to be embodied in a concrete atomic model. Again Lewis’ theory did not interest his Harvard mentors, who, like most American chemists of that time, had no taste for such ...
The cubical atom was an early atomic model in which electrons were positioned at the eight corners of a cube in a non-polar atom or molecule. This theory was developed in 1902 by Gilbert N. Lewis and published in 1916 in the article "The Atom and the Molecule" and used to account for the phenomenon of valency. [1] Lewis' theory was based on ...
[1] [2] [3] Introduced by Gilbert N. Lewis in his 1916 article The Atom and the Molecule, a Lewis structure can be drawn for any covalently bonded molecule, as well as coordination compounds. [4] Lewis structures extend the concept of the electron dot diagram by adding lines between atoms to represent shared pairs in a chemical bond.
Gilbert N. Lewis To explain the octet rule (1893), he developed the " cubical atom " theory in which electrons in the form of dots were positioned at the corner of a cube and suggested that single, double, or triple " bonds " result when two atoms are held together by multiple pairs of electrons (one pair for each bond) located between the two ...
For example, NH 3 is a Lewis base, because it can donate its lone pair of electrons. Trimethylborane [(CH 3) 3 B] is a Lewis acid as it is capable of accepting a lone pair. In a Lewis adduct, the Lewis acid and base share an electron pair furnished by the Lewis base, forming a dative bond. [1]
Langmuir's most famous publication is the 1919 article "The Arrangement of Electrons in Atoms and Molecules" in which, building on Gilbert N. Lewis's cubical atom theory and Walther Kossel's chemical bonding theory, he outlined his "concentric theory of atomic structure". [3]
Lewis's theory of chemical bonding continued to evolve and, in 1916, he published his seminal article "The Atom of the Molecule", which suggested that a chemical bond is a pair of electrons shared by two atoms. Lewis's model equated the classical chemical bond with the sharing of a pair of electrons between the two bonded atoms. Lewis ...
Gilbert N. Lewis and Merle Randall publish Thermodynamics and the Free Energy of Chemical Substances, first modern treatise on chemical thermodynamics. [103] 1923 Gilbert N. Lewis develops the electron pair theory of acid/base reactions. [101] 1924 Louis de Broglie introduces the wave-model of atomic structure, based on the ideas of wave ...