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Alternatively, by minimizing the change in free energy of de-mixing in regards to composition (=), the spinodal curve is defined. The conditions of the mixture in comparison to the two curves defines the phase separation mechanism: nucleation-growth of coacervate droplets (when the binodal region is crossed slowly) and spinodal decomposition.
A sol is a colloidal suspension made out of tiny solid particles [1] in a continuous liquid medium. Sols are stable, so that they do not settle down when left undisturbed, and exhibit the Tyndall effect, which is the scattering of light by the particles in the colloid. The size of the particles can vary from 1 nm - 100 nm.
The coagulation of gold sol results in an increase in particle size, indicated by a colour change from red to blue or purple. The higher the gold number, the lower the protective power of the colloid, because a greater amount of colloid is required to prevent coagulation. The gold number of some colloids are given below.
Dissolution of small crystals or sol particles and the redeposition of the dissolved species on the surfaces of larger crystals or sol particles was first described by Wilhelm Ostwald in 1896. [4] [5] For colloidal systems, Ostwald ripening is also found in water-in-oil emulsions, while flocculation is found in oil-in-water emulsions. [6]
The magnitude of the equilibrium constant depends on the Gibbs free energy change for the reaction. [2] So, when the free energy change is large (more than about 30 kJ mol −1), the equilibrium constant is large (log K > 3) and the concentrations of the reactants at equilibrium are very small. Such a reaction is sometimes considered to be an ...
When lyophilic sols are added to lyophobic sols, depending on their sizes, either lyophobic sol is adsorbed in the surface of lyophilic sol or lyophilic sol is adsorbed on the surface of lyophobic sol. The layer of the protective colloid prevents direct collision between the hydrophobic colloidal particles and thus prevents coagulation. [1]
Particle agglomeration can be a reversible or irreversible process. Particle agglomerates defined as "hard agglomerates" are more difficult to redisperse to the initial single particles. In the course of agglomeration, the agglomerates will grow in size, and as a consequence they may settle to the bottom of the container, which is referred to ...
A colloid is stable if the interaction energy due to attractive forces between the colloidal particles is less than kT, where k is the Boltzmann constant and T is the absolute temperature. If this is the case, then the colloidal particles will repel or only weakly attract each other, and the substance will remain a suspension.