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Nitric oxide (nitrogen oxide or nitrogen monoxide [1]) is a colorless gas with the formula NO. It is one of the principal oxides of nitrogen . Nitric oxide is a free radical : it has an unpaired electron , which is sometimes denoted by a dot in its chemical formula ( • N=O or • NO).
Due to relatively weak N–O bonding, all nitrogen oxides are unstable with respect to N 2 and O 2, which is the principle behind the catalytic converter, and prevents the oxygen and nitrogen in the atmosphere from combusting.
Nitrogen oxides are released during manufacturing of nitrogen fertilizers. Though nitrous oxide is emitted during its application, it is then reacted in atmosphere to form nitrogen oxides. This third source is attributed to the reaction of atmospheric nitrogen, N 2, with radicals such as C, CH, and CH 2 fragments derived from fuel, [26] rather ...
One other possible oxide that has not yet been synthesised is oxatetrazole (N 4 O), an aromatic ring. [15] Nitrous oxide (N 2 O), better known as laughing gas, is made by thermal decomposition of molten ammonium nitrate at 250 °C. This is a redox reaction and thus nitric oxide and nitrogen are also produced as byproducts.
Although most metal oxides are crystalline solids, many non-metal oxides are molecules. Examples of molecular oxides are carbon dioxide and carbon monoxide. All simple oxides of nitrogen are molecular, e.g., NO, N 2 O, NO 2 and N 2 O 4. Phosphorus pentoxide is a more complex molecular oxide with a deceptive name, the real formula being P 4 O 10.
[5] [6] Nitric oxide and hydrogen sulfide are highly reactive with numerous molecular targets, whereas carbon monoxide is relatively stable and metabolically inert predominately limited to interacting with ferrous ion complexes within mammalian organisms. [7] The scope of biological functions are different across biological systems. [8] [9]
Since nitrogen is more electronegative than carbon, metal-nitrosyl complexes tend to be more electrophilic than related metal carbonyl complexes. Nucleophiles often add to the nitrogen. [2] The nitrogen atom in bent metal nitrosyls is basic, thus can be oxidized, alkylated, and protonated, e.g.: (Ph 3 P) 2 (CO)ClOsNO + HCl → (Ph 3 P) 2 (CO ...
Lead(II) oxide – PbO; Lead dioxide – PbO 2; Lithium oxide – Li 2 O; Magnesium oxide – MgO; Potassium oxide – K 2 O; Rubidium oxide – Rb 2 O; Sodium oxide – Na 2 O; Strontium oxide – SrO; Tellurium dioxide – TeO 2; Uranium(IV) oxide – UO 2 (only simple oxides, oxyhalides, and related compounds, not hydroxides, carbonates ...