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R-22 use is being phased out in developing countries, where it is largely used for air conditioning applications. R-22 is prepared from chloroform: HCCl 3 + 2 HF → HCF 2 Cl + 2 HCl. An important application of R-22 is as a precursor to tetrafluoroethylene. This conversion involves pyrolysis to give difluorocarbene, which dimerizes: [3]
R-410A was invented and patented by Allied Signal (now Honeywell) in 1991. [5] Other producers around the world have been licensed to manufacture and sell R-410A. [6] R-410A was successfully commercialized in the air conditioning segment by a combined effort of Carrier Corporation, Emerson Climate Technologies, Inc., Copeland Scroll Compressors (a division of Emerson Electric Company), and ...
R-438A (MO-99) is a R-22 replacement. [71] R-123 HCFC-123 CHCl 2 CF 3: 2,2-Dichloro-1,1,1-trifluoroethane: 292 79 US phase-out Used in large tonnage centrifugal chiller applications. All U.S. production and import of virgin HCFCs will be phased out by 2030, with limited exceptions. [72] R-123 refrigerant was used to retrofit some chiller that ...
Chlorodifluoromethane (R-22 or HCFC-22), a type of Freon. [9] [10] Dichlorodifluoromethane (R-12 or CFC-12), the most commonly used Freon brand refrigerant prior to its ban in many countries in 1996 and total ban in 2010. 1,1,1,2-Tetrafluoroethane (R-134a or HFC-134a), one of the main replacements for the formerly widespread R-12.
For example, R-22 has one carbon atom, one hydrogen atom (2−1 = 1), two fluorine atoms, and one chlorine atom (4−2−1 = 1), so it is chlorodifluoromethane, while R-134 has two carbon atoms (2−1 = 1), two hydrogen atoms (3−1 = 2), four fluorine atoms, and no chlorine atoms (6−2−4 = 0), so it is one of the tetrafluoroethanes. This ...
Because of its reduced global warming potential (GWP), R-454B is intended to be an alternative to refrigerant R-410A in new equipment. [2] [3] [4] R-454B has a GWP of 466, which is 78 percent lower than R-410A's GWP of 2088. [2] R-454B is non-toxic and mildly flammable, with an ASHRAE safety classification of A2L. In the United States, it is ...
Chlorodifluoromethane (R-22), for example, has an ODP of 0.05. CFC 11, or R-11 has the maximum potential amongst chlorocarbons because of the presence of three chlorine atoms in the molecule. The first proposal of ODP came from Wuebbles in 1983. It was defined as a measure of destructive effects of a substance compared to a reference substance. [1]
Polyolester oil (POE oil) is a type of wax-free synthetic oils used in refrigeration compressors that is compatible with the refrigerants R-134a, R-410A, and R-12. [1] POE oils are used as a lubricant in systems using the refrigerant HFC-134a when replacing CFC-12 , as these systems traditionally use mineral oil , [ 2 ] which HFC-134a does not ...