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Pourbaix diagram of iron. [1] The Y axis corresponds to voltage potential. In electrochemistry, and more generally in solution chemistry, a Pourbaix diagram, also known as a potential/pH diagram, E H –pH diagram or a pE/pH diagram, is a plot of possible thermodynamically stable phases (i.e., at chemical equilibrium) of an aqueous electrochemical system.
The chloralkali process has been in use since the 19th century and is a primary industry in the United States, Western Europe, and Japan. [4] [5] It has become the principal source of chlorine during the 20th century. [6]
Diagram showing the solubility of lead in chloride media. The lead concentrations are plotted as a function of the total chloride present. [12] Pourbaix diagram for lead in chloride (0.1 M) media [12]
Chlorine can be manufactured by the electrolysis of a sodium chloride solution , which is known as the Chloralkali process. The production of chlorine results in the co-products caustic soda (sodium hydroxide, NaOH) and hydrogen gas (H 2). These two products, as well as chlorine itself, are highly reactive.
A Frost diagram or Frost–Ebsworth diagram is a type of graph used by inorganic chemists in electrochemistry to illustrate the relative stability of a number of different oxidation states of a particular substance.
Similar to Pourbaix diagrams for the speciation of redox species as a function of the redox potential and the pH, ionic partition diagrams indicate in which phase an acid or a base is predominantly present in a biphasic system as a function of the Galvani potential difference between the two phases and the pH of the aqueous solution. One of the ...
The pressure on a pressure-temperature diagram (such as the water phase diagram shown above) is the partial pressure of the substance in question. A phase diagram in physical chemistry , engineering , mineralogy , and materials science is a type of chart used to show conditions (pressure, temperature, etc.) at which thermodynamically distinct ...
A Latimer diagram of a chemical element is a summary of the standard electrode potential data of that element. This type of diagram is named after Wendell Mitchell Latimer (1893–1955), an American chemist.