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  2. Multiplicity (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Multiplicity_(chemistry)

    The triplet consists of three states with spin components +1, 0 and –1 along the direction of the total orbital angular momentum, which is also 1 as indicated by the letter P. The total angular momentum quantum number J can vary from L+S = 2 to L–S = 0 in integer steps, so that J = 2, 1 or 0.

  3. Singlet state - Wikipedia

    en.wikipedia.org/wiki/Singlet_state

    The ability of positronium to form both singlet and triplet states is described mathematically by saying that the product of two doublet representations (meaning the electron and positron, which are both spin-1/2 doublets) can be decomposed into the sum of an adjoint representation (the triplet or spin 1 state) and a trivial representation (the ...

  4. Triplet state - Wikipedia

    en.wikipedia.org/wiki/Triplet_state

    Examples of atoms in singlet, doublet, and triplet states. In quantum mechanics, a triplet state, or spin triplet, is the quantum state of an object such as an electron, atom, or molecule, having a quantum spin S = 1. It has three allowed values of the spin's projection along a given axis m S = −1, 0, or +1, giving the name "triplet".

  5. Doublet state - Wikipedia

    en.wikipedia.org/wiki/Doublet_state

    Examples of atoms in singlet, doublet, and triplet states.. In quantum mechanics, a doublet is a composite quantum state of a system with an effective spin of 1/2, such that there are two allowed values of the spin component, −1/2 and +1/2.

  6. Molecular orbital diagram - Wikipedia

    en.wikipedia.org/wiki/Molecular_orbital_diagram

    As in diboron, these two unpaired electrons have the same spin in the ground state, which is a paramagnetic diradical triplet oxygen. The first excited state has both HOMO electrons paired in one orbital with opposite spins, and is known as singlet oxygen. MO diagram of dioxygen triplet ground state

  7. Singlet fission - Wikipedia

    en.wikipedia.org/wiki/Singlet_fission

    Singlet fission is a spin-allowed process, unique to molecular photophysics, whereby one singlet excited state is converted into two triplet states.The phenomenon has been observed in molecular crystals, aggregates, disordered thin films, and covalently-linked dimers, where the chromophores are oriented such that the electronic coupling between singlet and the double triplet states is large.

  8. Intersystem crossing - Wikipedia

    en.wikipedia.org/wiki/Intersystem_crossing

    In a triplet state the excited electron is no longer paired with the ground state electron; that is, they are parallel (same spin). Since excitation to a triplet state involves an additional "forbidden" spin transition, it is less probable that a triplet state will form when the molecule absorbs radiation. Singlet and triplet energy levels.

  9. Multiplet - Wikipedia

    en.wikipedia.org/wiki/Multiplet

    A spin singlet is a trivial representation, a spin doublet is a fundamental representation and a spin triplet is in the vector representation or adjoint representation. In QCD, quarks are in a multiplet of SU(3), specifically the three-dimensional fundamental representation.