enow.com Web Search

Search results

  1. Results from the WOW.Com Content Network
  2. Optical rotation - Wikipedia

    en.wikipedia.org/wiki/Optical_rotation

    Optical rotation, also known as polarization rotation or circular birefringence, is the rotation of the orientation of the plane of polarization about the optical axis of linearly polarized light as it travels through certain materials. Circular birefringence and circular dichroism are the manifestations of optical activity.

  3. Mutarotation - Wikipedia

    en.wikipedia.org/wiki/Mutarotation

    For example, if a solution of β-D-glucopyranose is dissolved in water, its specific optical rotation will be +18.7°. Over time, some of the β-D-glucopyranose will undergo mutarotation to become α-D-glucopyranose, which has an optical rotation of +112.2°. The rotation of the solution will increase from +18.7° to an equilibrium value of +52 ...

  4. Specific rotation - Wikipedia

    en.wikipedia.org/wiki/Specific_rotation

    Specific rotation is an intensive property, distinguishing it from the more general phenomenon of optical rotation. As such, the observed rotation ( α ) of a sample of a compound can be used to quantify the enantiomeric excess of that compound, provided that the specific rotation ( [α] ) for the enantiopure compound is known.

  5. Stereoisomerism - Wikipedia

    en.wikipedia.org/wiki/Stereoisomerism

    The other refers to Optical rotation, when looking at the source of light, the rotation of the plane of polarization may be either to the right (dextrorotary — d-rotary, represented by (+), clockwise), or to the left (levorotary — l-rotary, represented by (−), counter-clockwise) depending on which stereoisomer is dominant. For instance ...

  6. Chiral drugs - Wikipedia

    en.wikipedia.org/wiki/Chiral_drugs

    Chiral drugs that are equimolar (1:1) mixture of enantiomers are called racemic drugs and these are obviously devoid of optical rotation. The most commonly encountered stereogenic unit, [2] that confers chirality to drug molecules are stereogenic center. Stereogenic center can be due to the presence of tetrahedral tetra coordinate atoms (C,N,P ...

  7. Optical rotatory dispersion - Wikipedia

    en.wikipedia.org/wiki/Optical_rotatory_dispersion

    Short wavelengths are rotated more than longer wavelengths, per unit of distance. Because the wavelength of light determines its color, the variation of color with distance through the tube is observed. [citation needed] This dependence of specific rotation on wavelength is called optical rotatory dispersion. In all materials the rotation ...

  8. Anomer - Wikipedia

    en.wikipedia.org/wiki/Anomer

    For example, regardless of the configuration of the starting D-glucose, a solution will gradually move towards being a mixture of approximately 64% β-D-glucopyranoside and 36% of α-D-glucopyranose. As the ratio changes, the optical rotation of the mixture changes; this phenomenon is called mutarotation.

  9. Hexose - Wikipedia

    en.wikipedia.org/wiki/Hexose

    The "α" and "β" forms, which are not enantiomers, will usually crystallize separately as distinct species. For example, D-glucose forms an α crystal that has specific rotation of +112° and melting point of 146 °C, as well as a β crystal that has specific rotation of +19° and melting point of 150 °C. [4]