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The Hall–Héroult process is the major industrial process for smelting aluminium. It involves dissolving aluminium oxide (alumina) (obtained most often from bauxite , aluminium 's chief ore, through the Bayer process ) in molten cryolite and electrolyzing the molten salt bath, typically in a purpose-built cell.
The process produces a quantity of fluoride waste: perfluorocarbons and hydrogen fluoride as gases, and sodium and aluminium fluorides and unused cryolite as particulates. This can be as small as 0.5 kg per tonne of aluminium in the best plants in 2007, up to 4 kg per tonne of aluminium in older designs in 1974.
Aluminium recycling is the process in which secondary commercial aluminium is created from scrap or other forms of end-of-life or otherwise unusable aluminium. [1] It involves re-melting the metal, which is cheaper and more energy-efficient than the production of virgin aluminium by electrolysis of alumina (Al 2 O 3 ) refined from raw bauxite ...
Hall and Heroult share credit for inventing aluminium electrolysis. [9] The Hall–Heroult method is the primary method of producing modern aluminium and requires high purity alumina to produce aluminium. The Bayer process produces high purity alumina which is then used in the Hall–Heroult process as the main raw material. [9]
Molten cryolite is used as a solvent for aluminium oxide (Al 2 O 3) in the Hall–Héroult process, used in the refining of aluminium. It decreases the melting point of aluminium oxide from 2000–2500 °C to 900–1000 °C, and increases its conductivity [ 18 ] thus making the extraction of aluminium more economical.
Primary aluminium smelting is the process of extracting aluminium from aluminium oxide (also known as alumina). The process takes place in electrolytic cells that are known as pots. The pots are made up of steel shells with two linings, an outer insulating or refractory lining and an inner carbon lining that acts as the cathode of the ...
The same year, in the United States, Charles Martin Hall (1863–1914) was discovering the same process. Because of this, the process was called the Hall–Heroult process . Héroult's second most important contribution is the first commercially successful electric arc furnace (EAF) for steel in 1900.
An electrolytic process is the use of electrolysis industrially to refine metals or compounds at a high purity and low cost. Some examples are the Hall-Héroult process [ 1 ] used for aluminium , or the production of hydrogen from water .