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Hess's law states that the change of enthalpy in a chemical reaction is the same regardless of whether the reaction takes place in one step or several steps, provided the initial and final states of the reactants and products are the same. Enthalpy is an extensive property, meaning that its value is proportional to the system size. [4]
Defining equation (physical chemistry) List of equations in classical mechanics; ... Variables commonly used in physics; Equation solving; Theory of equations
However, if one searches for real solutions, there are two solutions, √ 2 and – √ 2; in other words, the solution set is {√ 2, − √ 2}. When an equation contains several unknowns, and when one has several equations with more unknowns than equations, the solution set is often infinite. In this case, the solutions cannot be listed.
Theoretical chemistry requires quantities from core physics, such as time, volume, temperature, and pressure.But the highly quantitative nature of physical chemistry, in a more specialized way than core physics, uses molar amounts of substance rather than simply counting numbers; this leads to the specialized definitions in this article.
where P is the pressure of the gas, V is the volume of the gas, and k is a constant for a particular temperature and amount of gas.. Boyle's law states that when the temperature of a given mass of confined gas is constant, the product of its pressure and volume is also constant.
[4] Perhaps the greatest success of the kinetic theory of gases, as it came to be called, was the discovery that for gases, the temperature as measured on the Kelvin (absolute) temperature scale is directly proportional to the average kinetic energy of the gas molecules. Graham's law for diffusion could thus be understood as a consequence of ...
Le Chatelier–Braun principle analyzes the qualitative behaviour of a thermodynamic system when a particular one of its externally controlled state variables, say , changes by an amount , the 'driving change', causing a change , the 'response of prime interest', in its conjugate state variable , all other externally controlled state variables remaining constant.
The simplest equations to solve are linear equations that have only one variable. They contain only constant numbers and a single variable without an exponent. As an example, consider: Problem in words: If you double the age of a child and add 4, the resulting answer is 12. How old is the child?