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Arndt–Eistert reaction is a series of chemical reactions designed to convert a carboxylic acid to a higher carboxylic acid homologue (i.e. contains one additional carbon atom) Kowalski ester homologation, an alternative to the Arndt-Eistert synthesis. Has been used to convert β-amino esters from α-amino esters through an ynolate ...
Alkenes are generally colorless non-polar compounds, somewhat similar to alkanes but more reactive. The first few members of the series are gases or liquids at room temperature. The simplest alkene, ethylene (C 2 H 4) (or "ethene" in the IUPAC nomenclature) is the organic compound produced on the largest scale industrially. [5]
The homologous series of straight-chained alkanes begins methane (CH 4), ethane (C 2 H 6), propane (C 3 H 8), butane (C 4 H 10), and pentane (C 5 H 12). In that series, successive members differ in mass by an extra methylene bridge (-CH 2 - unit) inserted in the chain. Thus the molecular mass of each member differs by 14 atomic mass units ...
2 994 664 179 967 370 611: 3.486 951 955 119 47 × 10 21: C 51 H 104: n-henpentacontane: 52 8 031 081 780 535 296 591: 1.092 126 741 043 54 × 10 22: C 52 H 106: n-dopentacontane: 53 2.155 777 191 357 26 × 10 19: 3.423 721 299 907 32 × 10 22: C 53 H 108: n-tripentacontane: 54 5.791 918 087 314 84 × 10 19: 1.074 254 564 589 75 × 10 23: C 54 ...
Ketene cycloadditions proceed by a concerted, [2+2] cycloaddition mechanism. Ketenes, unlike most alkenes, can align antarafacially with respect to other alkenes. Thus, the suprafacial- antarafacial geometry required for concerted, thermal [2+2] cycloaddition can be achieved in reactions of ketenes. [4]
The double bond of an alpha olefin is between the #1 and #2 (IUPAC) or α and β (common) carbon atoms. In organic chemistry , terminal alkenes ( alpha-olefins , α-olefins , or 1-alkenes ) are a family of organic compounds which are alkenes (also known as olefins) with a chemical formula C x H 2 x , distinguished by having a double bond at the ...
the butterfly bending angle or folding angle ψ (c) is defined as the angle between two planes and can be obtained by averaging the two torsional angles R 1 C=CR 3 and R 2 C=CR 4. In alkenes 1.2 and 1.3 these angles are determined with X-ray crystallography as respectively 32.4°/22.7° and 27.3°/35.6°. Although stable, these alkenes are very ...
In organic chemistry, alkylidene is a general term for divalent functional groups of the form R 2 C=, where each R is an alkane or hydrogen. [1] They can be considered the functional group corresponding to mono- or disubstituted divalent carbenes (known as alkylidenes), [2] or as the result of removing two hydrogen atoms from the same carbon atom in an alkane.