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The process flow diagram below depicts a typical semi-regenerative catalytic reforming unit. Schematic diagram of a typical semi-regenerative catalytic reformer unit in a petroleum refinery. The liquid feed (at the bottom left in the diagram) is pumped up to the reaction pressure (5–45 atm) and is joined by a stream of hydrogen-rich recycle gas.
Catalytic reforming usually utilizes a feedstock naphtha that contains non-aromatic hydrocarbons with 6 to 12 carbon atoms and typically produces a reformate product containing C 6 to C 8 aromatics (benzene, toluene, xylenes) as well as paraffins and heavier aromatics containing 9 to 12 carbon atoms.
This is a problem in the catalytic reforming of petroleum and the steam reforming of natural gas. The reaction is named after the French chemist, Octave Leopold Boudouard (1872–1923), who investigated this equilibrium in 1905. [6]
Chemical looping systems can directly be engaged as an effective means for syngas production. Compared to the conventional partial oxidation (POX) or autothermal reforming (ATR) processes, the key advantage of the chemical looping reforming (CLR) process is the elimination of the air separation unit (ASU) for oxygen production. The gaseous fuel ...
In CPOX (catalytic partial oxidation) the use of a catalyst reduces the required temperature to around 800°C – 900°C. [citation needed] The choice of reforming technique depends on the sulfur content of the fuel being used. CPOX can be employed if the sulfur content is below 50 ppm. A higher sulfur content can poison the catalyst, so the ...
Petroleum naphtha is an intermediate hydrocarbon liquid stream derived from the refining of crude oil [1] [2] [3] with CAS-no 64742-48-9. [4] It is most usually desulfurized and then catalytically reformed, which rearranges or restructures the hydrocarbon molecules in the naphtha as well as breaking some of the molecules into smaller molecules to produce a high-octane component of gasoline (or ...
Catalytic reforming of all materials occurred without the requirement of an external heat source while operating at 500–900 °C. Under optimal conditions, 50% of all atomic hydrogen and 50% of all atomic carbon can be converted to molecular H 2 and carbon monoxide in as little time as 30 milliseconds.
Processes included the Lurgi Process, catalytic reforming, the catalytic rich gas process, steam reforming of rich gas, and the gas recycle hydrogenator process. [17] The catalytic rich gas process used natural gas as a feedstock to manufacture town gas. These facilities utilised the chemical reaction processes described above.