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In stereochemistry, enantiomeric excess (ee) is a measurement of purity used for chiral substances. It reflects the degree to which a sample contains one enantiomer in greater amounts than the other.
The difference between the two peak potentials (E p), ΔE p, is of particular interest. ΔE p = E pa - E pc > 0. This difference mainly results from the effects of analyte diffusion rates. In the ideal case of a reversible 1e- couple (i.e., Nernstian), ΔE p is 57 mV and the full-width half-max of the forward scan peak is 59 mV. Typical values ...
In electrochemistry, the electrochemical potential of electrons (or any other species) is the total potential, including both the (internal, nonelectrical) chemical potential and the electric potential, and is by definition constant across a device in equilibrium, whereas the chemical potential of electrons is equal to the electrochemical ...
The invariance properties of molecular descriptors can be defined as the ability of the algorithm for their calculation to give a descriptor value that is independent of the particular characteristics of the molecular representation, such as atom numbering or labeling, spatial reference frame, molecular conformations, etc. Invariance to molecular numbering or labeling is assumed as a minimal ...
For the definition reaction series δ was set to 1 and E s for the reference reaction was set to zero. This equation is combined with the equation for σ* to give the full Taft equation. From comparing the E s values for methyl, ethyl, isopropyl, and tert-butyl, it is seen that the value
The CRC Handbook of Chemistry and Physics is a comprehensive one-volume reference resource for science research. First published in 1914, it is currently (as of 2024 [update] ) in its 105th edition, published in 2024.
The system of this measurement is usually the same as that of standard voltammetry.The potential between the working electrode and the reference electrode is changed as a pulse from an initial potential to an interlevel potential and remains at the interlevel potential for about 5 to 100 milliseconds; then it changes to the final potential, which is different from the initial potential.
In chromatography, the retardation factor (R) is the fraction of an analyte in the mobile phase of a chromatographic system. [1] In planar chromatography in particular, the retardation factor R F is defined as the ratio of the distance traveled by the center of a spot to the distance traveled by the solvent front. [2]