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The effect of temperature on the extent of the Boudouard reaction is indicated better by the value of the equilibrium constant than by the standard free energy of reaction. The value of log 10 ( K eq ) for the reaction as a function of temperature in Kelvin (valid between 500– 2200 K ) is approximately: [ 4 ]
In thermodynamics, a quasi-static process, also known as a quasi-equilibrium process (from Latin quasi, meaning ‘as if’ [1]), is a thermodynamic process that happens slowly enough for the system to remain in internal physical (but not necessarily chemical) thermodynamic equilibrium.
English: Alternative explanations of the punctuated equilibrium pattern of evolution observed in the fossil record. Both macromutation and relatively rapid episodes of gradual evolution by natural selection could give the effect of apparently instantaneous change, since 10,000 years barely registers in the fossil record.
The factor of 1/4 in the above formula comes from the fact that only a single hemisphere is lit at any moment in time (creates a factor of 1/2), and from integrating over angles of incident sunlight on the lit hemisphere (creating another factor of 1/2). [6]
The phase diagram shows, in pressure–temperature space, the lines of equilibrium or phase boundaries between the three phases of solid, liquid, and gas. The curves on the phase diagram show the points where the free energy (and other derived properties) becomes non-analytic: their derivatives with respect to the coordinates (temperature and ...
A central aim in equilibrium thermodynamics is: given a system in a well-defined initial state of thermodynamic equilibrium, subject to accurately specified constraints, to calculate, when the constraints are changed by an externally imposed intervention, what the state of the system will be once it has reached a new equilibrium. An equilibrium ...
Le Chatelier–Braun principle analyzes the qualitative behaviour of a thermodynamic system when a particular one of its externally controlled state variables, say , changes by an amount , the 'driving change', causing a change , the 'response of prime interest', in its conjugate state variable , all other externally controlled state variables remaining constant.
In a system that is in its own state of internal thermodynamic equilibrium, not only is there an absence of macroscopic change, but there is an “absence of any tendency toward change on a macroscopic scale.” [1] Systems in mutual thermodynamic equilibrium are simultaneously in mutual thermal, mechanical, chemical, and radiative equilibria ...