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The reaction of (MDI) and polyol takes place at higher temperatures compared with the reaction temperature for the manufacture of PUR. At these elevated temperatures and in the presence of specific catalysts, MDI will first react with itself, producing a stiff, ring molecule, which is a reactive intermediate (a tri-isocyanate isocyanurate compound).
Spray foam (expanding foam in the UK) is a chemical product created by a chemical reaction of two component parts, commonly referred to as side A and side B. [1] Side A contains very reactive chemicals known as isocyanate. Side B contains a polyol, which reacts with isocyanates to make polyurethane, and a mixture of other chemicals, including ...
An isocyanate at the 4-position is approximately four times more reactive than the group at the 2-position due to steric hindrance. [4] In 4,4′-MDI and 2,2′-MDI, the two isocyanate groups are equivalent to each other, but in 2,4′-MDI the two groups display highly differing reactivities. MDI isomers and polymer
The isocyanate functional group. In organic chemistry, isocyanate is the functional group with the formula R−N=C=O. Organic compounds that contain an isocyanate group are referred to as isocyanates. An organic compound with two isocyanate groups is known as a diisocyanate.
Factors affecting catalyst selection include balancing three reactions: urethane (polyol+isocyanate, or gel) formation, the urea (water+isocyanate, or "blow") formation, or the isocyanate trimerization reaction (e.g., using potassium acetate, to form isocyanurate rings). A variety of specialized catalysts have been developed. [33] [34] [35]
Moisture cured polyurethane–urea coatings have been made by reacting 1,2,3-triazole rich polyether polyols with HMDI at NCO/OH eq. ratio of 1.2 to obtain isocyanate-terminated polyurethane prepolymers. The prepolymers were cured under atmospheric moisture to make polyurethane–urea free films.
The flexible polyurethane foam (FPUF) is produced from the reaction of polyols and isocyanates, a process pioneered in 1937. [7] Depending on the application the foam will be used for, a series of additives are necessary to produce high-quality PU foam products. FPUF is a versatile material that can be tailored to exhibit different properties.
An isocyanate (usually a diisocyanate) is reacted with a polyol. All types of polyol may in theory be used to produce polyurethane prepolymers. [2] [3] [4] ...