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Fluorine forms a great variety of chemical compounds, within which it always adopts an oxidation state of −1. With other atoms, fluorine forms either polar covalent bonds or ionic bonds. Most frequently, covalent bonds involving fluorine atoms are single bonds, although at least two examples of a higher order bond exist. [2]
Fluorine has a rich chemistry, encompassing organic and inorganic domains. It combines with metals, nonmetals, metalloids, and most noble gases. [97] Fluorine's high electron affinity results in a preference for ionic bonding; when it forms covalent bonds, these are polar, and almost always single. [98] [99] [note 10]
In the vapour phase the SrF 2 molecule is non-linear with an F−Sr−F angle of approximately 120°. [5] This is an exception to VSEPR theory which would predict a linear structure. Ab initio calculations have been cited to propose that contributions from d orbitals in the shell below the valence shell are responsible. [ 6 ]
[1] [2] [3] Introduced by Gilbert N. Lewis in his 1916 article The Atom and the Molecule, a Lewis structure can be drawn for any covalently bonded molecule, as well as coordination compounds. [4] Lewis structures extend the concept of the electron dot diagram by adding lines between atoms to represent shared pairs in a chemical bond.
Barium fluoride is an inorganic compound with the formula Ba F 2.It is a colorless solid that occurs in nature as the rare mineral frankdicksonite. [9] Under standard conditions it adopts the fluorite structure and at high pressure the PbCl 2 structure. [10]
Magnesium fluoride is an ionically bonded inorganic compound with the formula Mg F 2.The compound is a colorless to white crystalline salt and is transparent over a wide range of wavelengths, with commercial uses in optics that are also used in space telescopes.
Difluorides are chemical compounds with two fluorine atoms per molecule (or per formula unit). Metal difluorides are all ionic. Despite being highly ionic, the alkaline earth metal difluorides generally have extremely high lattice stability and are thus insoluble in water. The exception is beryllium difluoride.
Oxygen difluoride is a chemical compound with the formula OF 2. As predicted by VSEPR theory, the molecule adopts a bent molecular geometry. [citation needed] It is a strong oxidizer and has attracted attention in rocketry for this reason. [5] With a boiling point of −144.75 °C, OF 2 is the most volatile (isolable) triatomic compound. [6]
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