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In coordination chemistry, a coordinate covalent bond, [1] also known as a dative bond, [2] dipolar bond, [1] or coordinate bond [3] is a kind of two-center, two-electron covalent bond in which the two electrons derive from the same atom. The bonding of metal ions to ligands involves this kind of interaction. [4]
This bonding scheme is succinctly summarized by the following two resonance structures: I—I···I − ↔ I − ···I—I (where "—" represents a single bond and "···" represents a "dummy bond" with formal bond order 0 whose purpose is only to indicate connectivity), which when averaged reproduces the I—I bond order of 0.5 obtained ...
However, these ligands also form dative covalent bonds like the L-type. [2] This type of ligand is not usually used because in certain situations it can be written in terms of L and X. For example, if a Z ligand is accompanied by an L type, it can be written as X 2. Examples of these ligands are Lewis acids, such as BR 3. [3]
The phase velocity is the rate at which the phase of the wave propagates in space. The group velocity is the rate at which the wave envelope, i.e. the changes in amplitude, propagates. The wave envelope is the profile of the wave amplitudes; all transverse displacements are bound by the envelope profile.
The MO diagram for dihydrogen. In the classic example of the H 2 MO, the two separate H atoms have identical atomic orbitals. When creating the molecule dihydrogen, the individual valence orbitals, 1s, either: merge in phase to get bonding orbitals, where the electron density is in between the nuclei of the atoms; or, merge out of phase to get antibonding orbitals, where the electron density ...
The concept that matter behaves like a wave was proposed by French physicist Louis de Broglie (/ d ə ˈ b r ɔɪ /) in 1924, and so matter waves are also known as de Broglie waves. The de Broglie wavelength is the wavelength , λ , associated with a particle with momentum p through the Planck constant , h : λ = h p . {\displaystyle \lambda ...
As such, the predicted shape and bond angle of sp 3 hybridization is tetrahedral and 109.5°. This is in open agreement with the true bond angle of 104.45°. The difference between the predicted bond angle and the measured bond angle is traditionally explained by the electron repulsion of the two lone pairs occupying two sp 3 hybridized orbitals.
Contributing structures of the carbonate ion. In chemistry, resonance, also called mesomerism, is a way of describing bonding in certain molecules or polyatomic ions by the combination of several contributing structures (or forms, [1] also variously known as resonance structures or canonical structures) into a resonance hybrid (or hybrid structure) in valence bond theory.