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The second law of thermodynamics is a physical law based on universal empirical observation concerning heat and energy interconversions.A simple statement of the law is that heat always flows spontaneously from hotter to colder regions of matter (or 'downhill' in terms of the temperature gradient).
The flow of heat is a form of energy transfer. Heat transfer is the natural process of moving energy to or from a system, other than by work or the transfer of matter. In a diathermal system, the internal energy can only be changed by the transfer of energy as heat: =.
Heat can flow into or out of a closed system by way of thermal conduction or of thermal radiation to or from a thermal reservoir, and when this process is effecting net transfer of heat, the system is not in thermal equilibrium. While the transfer of energy as heat continues, the system's temperature can be changing.
According to energy conservation and energy being a state function that does not change over a full cycle, the work from a heat engine over a full cycle is equal to the net heat, i.e. the sum of the heat put into the system at high temperature, q H > 0, and the waste heat given off at the low temperature, q C < 0. [93]
A traditional version of the second law of thermodynamics states: Heat does not spontaneously flow from a colder body to a hotter body. The second law refers to a system of matter and radiation, initially with inhomogeneities in temperature, pressure, chemical potential, and other intensive properties , that are due to internal 'constraints ...
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A contact equilibrium may be regarded also as an exchange equilibrium. There is a zero balance of rate of transfer of some quantity between the two systems in contact equilibrium. For example, for a wall permeable only to heat, the rates of diffusion of internal energy as heat between the two systems are equal and opposite.
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