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Sodium carbonate (also known as washing soda, soda ash and soda crystals) is the inorganic compound with the formula Na 2 CO 3 and its various hydrates.All forms are white, odourless, water-soluble salts that yield alkaline solutions in water.
A spectator ion is an ion that exists both as a reactant and a product in a chemical equation of an aqueous solution. [1]For example, in the reaction of aqueous solutions of sodium carbonate and copper(II) sulfate:
Sodium percarbonate or sodium carbonate peroxide is a chemical substance with empirical formula Na 2 H 3 CO 6. It is an adduct of sodium carbonate ("soda ash" or "washing soda") and hydrogen peroxide (that is, a perhydrate ) whose formula is more properly written as 2 Na 2 CO 3 · 3 H 2 O 2 .
The ammonia from reaction (III) is recycled back to the initial brine solution of reaction (I). The sodium bicarbonate (NaHCO 3) precipitate from reaction (I) is then converted to the final product, sodium carbonate (washing soda: Na 2 CO 3), by calcination (160–230 °C), producing water and carbon dioxide as byproducts:
Salt/common salt – a mineral, sodium chloride, NaCl, formed by evaporating seawater (impure form). Salt of tartar – potassium carbonate; also called potash. Salt of hartshorn/sal volatile – ammonium carbonate formed by distilling bones and horns. Tin salt – hydrated stannous chloride; see also spiritus fumans, another chloride of tin.
There are other reactions of carbonyl compounds similar to aldol condensation: When the base is an amine and the active hydrogen compound is sufficiently activated the reaction is called a Knoevenagel condensation. In a Perkin reaction the aldehyde is aromatic and the enolate generated from an anhydride.
One workaround to avoid this method is to reduce the carboxylic acid derivative all the way down to an alcohol, then oxidize the alcohol back to an aldehyde. Other alternatives include forming a thioester or a Weinreb amide, then reducing the new species to an aldehyde through the Fukuyama reduction or Weinreb reaction respectively, or using ...
The post-reaction mixture often consists of small amounts of leftover acid and alcohol, in addition to the desired ester. [13] Acid-base extraction can be used to easily separate out the acidic starting materials from the ester. By rinsing the crude product mixture with a weak base (e.g. sodium bicarbonate), the carboxylic acid and alcohol will ...