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2 FeCl 3 + Fe → 3 FeCl 2. A traditional synthesis of anhydrous ferrous chloride is the reduction of FeCl 3 with chlorobenzene: [25] 2 FeCl 3 + C 6 H 5 Cl → 2 FeCl 2 + C 6 H 4 Cl 2 + HCl. iron(III) chloride releases chlorine gas when heated above 160 °C, generating ferrous chloride: [16] 2FeCl 3 → 2FeCl 2 + Cl 2
Potassium ferrioxalate contains the iron(III) complex [Fe(C 2 O 4) 3] 3−. In chemistry, iron(III) or ferric refers to the element iron in its +3 oxidation state. Ferric chloride is an alternative name for iron(III) chloride (FeCl 3). The adjective ferrous is used instead for iron(II) salts, containing the cation Fe 2+.
For example, "ferrous sulfide" can refer to the 1:1 species (mineral name troilite) or a host of Fe-deficient derivatives . The mineral magnetite ("lode stone") is a mixed-valence compound with both Fe(II) and Fe(III), Fe 3 O 4.
Iron(II) complexes are less stable than iron(III) complexes but the preference for O-donor ligands is less marked, so that for example [Fe(NH 3) 6] 2+ is known while [Fe(NH 3) 6] 3+ is not. They have a tendency to be oxidized to iron(III) but this can be moderated by low pH and the specific ligands used. [17]
3 anion, whose chlorine atom is in the +5 oxidation state. The term can also refer to chemical compounds containing this anion, with chlorates being the salts of chloric acid . Other oxyanions of chlorine can be named "chlorate" followed by a Roman numeral in parentheses denoting the oxidation state of chlorine: e.g., the ClO −
Fe 2 O 3 + 3 CO → 2 Fe + 3 CO 2. Another redox reaction is the extremely exothermic thermite reaction with aluminium. [17] 2 Al + Fe 2 O 3 → 2 Fe + Al 2 O 3. This process is used to weld thick metals such as rails of train tracks by using a ceramic container to funnel the molten iron in between two sections of rail.
Ferric acetate is the iron compound with the formula Fe 3 O(O 2 CCH 3) 6 (H 2 O) 3]O 2 CCH 3. This red brown solid is the acetate salt of the coordination complex [Fe 3 O(OAc) 6 (H 2 O) 3] + (OAc − is CH 3 CO 2 −). Commonly, the salt is known as "basic iron acetate". [2] The formation of the red-brown complex was once used as a test for ...
The Fe 3+ ion in ferric citrate (as in many iron(III) carboxylates) is reduced by exposure to light, [8] especially blue and ultraviolet, to Fe 2+ (ferrous) ion with concomitant oxidation of the carboxyl group adjacent to the hydroxyl, yielding carbon dioxide and acetonedicarboxylate: 2 Fe 3+ + R 2-C(OH)-CO − 2 → 2 Fe 2+ + R 2-C=O + H + + CO 2