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Organic Reactions is a peer-reviewed book series that was established in 1942. It publishes detailed descriptions of useful organic reactions . Each article (called a chapter) is an invited review of the primary source material for the given reaction, and is written under tight editorial control, making it a secondary to tertiary‑level source.
Wiley, John & Sons, Incorporated, 1st Ed. 1962, 6th Ed. 1999 Description: A classic general textbook for an undergraduate course in inorganic chemistry Importance: This book is not only a good introduction to the subject, it was very different from earlier texts and "led to a fundamental shift in the way in which inorganic chemistry was studied ...
The reaction has since been modified to proceed in the presence of Lewis acids and common organic solvents such as THF and dichloromethane. Reactions generally run at room temperature for about an hour, and the yield ranges from 70%-80% based on the choice of Lewis acid and solvent. [10]
Reaction example of Chan–Lam coupling. Compound 1, a pyrrole, is coupled with aryl boronic acid, 2, to afford product 3, which is then carried forward to the target 4. The nitrile group of 2 does not poison the catalyst. Pyridine is the ligand used for the reaction. Although the reaction requires three days, it was carried out at room ...
In organic chemistry, cheletropic reactions, also known as chelotropic reactions, [2] are a type of pericyclic reaction (a chemical reaction that involves a transition state with a cyclic array of atoms and an associated cyclic array of interacting orbitals). [1] Specifically, cheletropic reactions are a subclass of cycloadditions.
The Wolff–Kishner reduction is a reaction used in organic chemistry to convert carbonyl functionalities into methylene groups. [1] [2] In the context of complex molecule synthesis, it is most frequently employed to remove a carbonyl group after it has served its synthetic purpose of activating an intermediate in a preceding step.
An organic group's migration propensity depends on its ability to stabilize negative charge: alkynyl > aryl ≈ alkenyl > primary alkyl > secondary alkyl > tertiary alkyl. [32] Bis(norbornyl)borane and 9-BBN are often hydroboration reagents for this reason — only the hydroborated olefin is likely to migrate upon nucleophilic activation.
The reaction proceeds first through an imidate intermediate and then undergoes Mumm rearrangement to afford the Passerini product. [ 13 ] [ 14 ] As the Mumm rearrangement requires a second carboxylic acid molecule, this mechanism classifies the Passerini reaction as an organocatalytic reaction.