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Composition of Earth's atmosphere by molecular count, excluding water vapor. Lower pie represents trace gases that together compose about 0.0434% of the atmosphere. [5] [6] [7] The three major constituents of Earth's atmosphere are nitrogen, oxygen, and argon. Water vapor accounts for roughly 0.25% of the atmosphere by mass.
Argon is extracted industrially by the fractional distillation of liquid air in a cryogenic air separation unit; a process that separates liquid nitrogen, which boils at 77.3 K, from argon, which boils at 87.3 K, and liquid oxygen, which boils at 90.2 K. About 700,000 tonnes of argon are produced worldwide every year. [25] [35]
Liquid nitrogen is a compact and readily transported source of dry nitrogen gas, as it does not require pressurization. Further, its ability to maintain temperatures far below the freezing point of water, specific heat of 1040 J ⋅kg −1 ⋅K −1 and heat of vaporization of 200 kJ⋅kg −1 makes it extremely useful in a wide range of ...
For example, in 2012, a young woman in England had to have her stomach removed after ingesting a cocktail made with liquid nitrogen. [109] Because the liquid-to-gas expansion ratio of nitrogen is 1:694 at 20 °C, a tremendous amount of force can be generated if liquid nitrogen is rapidly vaporised in an enclosed space. In an incident on January ...
A nitrogen generator Bottle of 4Å molecular sieves. Pressure swing adsorption provides separation of oxygen or nitrogen from air without liquefaction. The process operates around ambient temperature; a zeolite (molecular sponge) is exposed to high pressure air, then the air is released and an adsorbed film of the desired gas is released.
2 ion. The distance between one nitrogen and the argon atom is 2.2 Å. [9] The vibrational band origin for the nitrogen bond in ArN + 2 (V = 0 → 1) is at 2272.2564 cm −1 compared with N 2 + at 2175 and N 2 at 2330 cm −1. [9] In the process of photodissociation, it is three times more likely to yield Ar + + N 2 compared to Ar + N + 2. [30]
Different gases will have different mean free paths for molecules and electrons. This is because different molecules have ionization cross sections, that is, different effective diameters. Noble gases like helium and argon are monatomic, which makes them harder to ionize and tend to have smaller effective diameters. This gives them greater mean ...
Liquid nitrogen is a commonly used cryogenic liquid. [12] Nitrogen in the form of ammonia is a nutrient critical to most plants' survival. [12] Synthesis of ammonia accounts for about 1–2% of the world's energy consumption and the majority of reduced nitrogen in food. Phosphorus is used in matches and incendiary bombs. [12]