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Triphenylbismuthine is an organobismuth compound with the formula Bi(C 6 H 5) 3. It is a white, air-stable solid that is soluble in organic solvents. It is prepared by treatment of bismuth trichloride with phenylmagnesium bromide. [2] BiCl 3 + 3 C 6 H 5 MgBr 3 → Bi(C 6 H 5) 3 + 3 MgBrCl. Structurally it resembles related compounds such as ...
Tributylphosphine is the organophosphorus compound with the chemical formula P(CH 2 CH 2 CH 2 CH 3) 3, often abbreviated as PBu 3. It is a tertiary phosphine. It is an oily liquid at room temperature, with a nauseating odor. It reacts slowly with atmospheric oxygen, and rapidly with other oxidizing agents, to give tributylphosphine oxide.
Tetrakis(hydroxymethyl)phosphonium chloride (THPC) is an organophosphorus compound with the chemical formula [P(CH 2 OH) 4]Cl. It is a white water-soluble salt with applications as a precursor to fire-retardant materials [ 1 ] and as a microbiocide in commercial and industrial water systems.
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Ph 3 P + CH 3 Br → Ph 3 PCH 3 Br. Methyltriphenylphosphonium bromide is the principal precursor to methylenetriphenylphosphorane, a useful methylenating reagent. This conversion is achieved by treating methyltriphenylphosphonium bromide with strong base. [2] Ph 3 PCH 3 Br + BuLi → Ph 3 PCH 2 + LiBr + BuH
“Our test identifies very early stages of tau tangle formation — up to a decade before any tau clumps can show up on a brain scan,” explains senior author Thomas Karikari, Ph.D. The ...
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