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The affinity laws (also known as the "Fan Laws" or "Pump Laws") for pumps/fans are used in hydraulics, hydronics and/or HVAC to express the relationship between variables involved in pump or fan performance (such as head, volumetric flow rate, shaft speed) and power. They apply to pumps, fans, and hydraulic turbines. In these rotary implements ...
For semiconductor alloys it may be necessary to use Vegard's law to calculate these values. Once the relative positions of the conduction and valence bands for both semiconductors are known, Anderson's rule allows the calculation of the band offsets of both the valence band ( Δ E v {\displaystyle \Delta E_{\rm {v}}} ) and the conduction band ...
where we introduce a concise and historical name for this quantity, the "affinity", symbolized by A, as introduced by Théophile de Donder in 1923.(De Donder; Progogine & Defay, p. 69; Guggenheim, pp. 37, 240) The minus sign ensures that in a spontaneous change, when the change in the Gibbs free energy of the process is negative, the chemical ...
Vegard's law assumes that both components A and B in their pure form (i.e., before mixing) have the same crystal structure. Here, a A (1-x) B x is the lattice parameter of the solid solution, a A and a B are the lattice parameters of the pure constituents, and x is the molar fraction of B in the solid solution.
In thermodynamics, the Gibbs free energy (or Gibbs energy as the recommended name; symbol ) is a thermodynamic potential that can be used to calculate the maximum amount of work, other than pressure–volume work, that may be performed by a thermodynamically closed system at constant temperature and pressure.
The simplest inlet to a centrifugal compressor is typically a simple pipe. Depending upon its use/application inlets can be very complex. They may include other components such as an inlet throttle valve, a shrouded port, an annular duct (see Figure 1.1), a bifurcated duct, stationary guide vanes/airfoils used to straight or swirl flow (see Figure 1.1), movable guide vanes (used to vary pre ...
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In chemical physics and physical chemistry, chemical affinity is the electronic property by which dissimilar chemical species are capable of forming chemical compounds. [1] Chemical affinity can also refer to the tendency of an atom or compound to combine by chemical reaction with atoms or compounds of unlike composition.