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Relative volatility is a measure comparing the vapor pressures of the components in a liquid mixture of chemicals. This quantity is widely used in designing large industrial distillation processes. [ 1 ] [ 2 ] [ 3 ] In effect, it indicates the ease or difficulty of using distillation to separate the more volatile components from the less ...
In chemistry, volatility is a material quality which describes how readily a substance vaporizes. At a given temperature and pressure , a substance with high volatility is more likely to exist as a vapour , while a substance with low volatility is more likely to be a liquid or solid .
Distillation, also classical distillation, is the process of separating the component substances of a liquid mixture of two or more chemically discrete substances; the separation process is realized by way of the selective boiling of the mixture and the condensation of the vapors in a still.
Large-scale industrial distillation is rarely undertaken if the relative volatility is less than 1.05 with the volatile component being i and the less volatile component being j. [2] K values are widely used in the design calculations of continuous distillation columns for distilling multicomponent mixtures.
Greater deviations from Raoult's law make it easier to achieve significant changes in relative volatility with the addition of another component. In azeotropic distillation the volatility of the added component is the same as the mixture, and a new azeotrope is formed with one or more of the components based on differences in polarity. [2]
A fractionating column or fractional column is equipment used in the distillation of liquid mixtures to separate the mixture into its component parts, or fractions, based on their differences in volatility. Fractionating columns are used in small-scale laboratory distillations as well as large-scale industrial distillations.
Salt-effect distillation is a method of extractive distillation in which a salt is dissolved in the mixture of liquids to be distilled. The salt acts as a separating agent by raising the relative volatility of the mixture and by breaking any azeotropes that may otherwise form.
Fractionation at total reflux. The Fenske equation in continuous fractional distillation is an equation used for calculating the minimum number of theoretical plates required for the separation of a binary feed stream by a fractionation column that is being operated at total reflux (i.e., which means that no overhead product distillate is being withdrawn from the column).