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Triethylenetetramine (TETA and trien), also known as trientine when used medically, is an organic compound with the formula [CH 2 NHCH 2 CH 2 NH 2] 2. The pure free base is a colorless oily liquid, but, like many amines , older samples assume a yellowish color due to impurities resulting from air oxidation .
Tren is a common impurity in the more common triethylenetetramine ("trien"). As a trifunctional amine, tren forms a triisocyanate when derivatized with COCl 2. TREN is known to react fast in the presence of (aromatic) aldehydes to form an imine. During this process, water is formed, making it a condensation reaction.
In chemistry, the mass concentration ρ i (or γ i) is defined as the mass of a constituent m i divided by the volume of the mixture V. [1]= For a pure chemical the mass concentration equals its density (mass divided by volume); thus the mass concentration of a component in a mixture can be called the density of a component in a mixture.
Ligands of denticity greater than 6 are well known. The ligands 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetate (DOTA) and diethylene triamine pentaacetate (DTPA) are octadentate. They are particularly useful for binding lanthanide ions, which typically have coordination numbers greater than 6.
Diethylenetriamine (abbreviated Dien or DETA) and also known as 2,2’-Iminodi(ethylamine) [2]) is an organic compound with the formula HN(CH 2 CH 2 NH 2) 2.This colourless hygroscopic liquid is soluble in water and polar organic solvents, but not simple hydrocarbons.
The amine value is useful in helping determine the correct stoichiometry of a two component amine cure epoxy resin system. [6] [7] [8]It is the number of Nitrogens x 56.1 (Mwt of KOH) x 1000 (convert to milligrams) divided by molecular mass of the amine functional compound.
PMDTA is used to modify the reactivity of organolithium compounds, which deaggregate in the presence of Lewis bases to enhance their reactivity. [3] Commonly, the ditertiary amine TMEDA is used in these applications; it binds to the lithium center as a bidentate ligand.
Sometimes specific volume is expressed in terms of the number of cubic centimeters occupied by one gram of a substance. In this case, the unit is the centimeter cubed per gram (cm 3 /g or cm 3 ·g −1). To convert m 3 /kg to cm 3 /g, multiply by 1000; conversely, multiply by 0.001. Specific volume is inversely proportional to density.