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A primary standard in metrology is a standard that is sufficiently accurate such that it is not calibrated by or subordinate to other standards. Primary standards are defined via other quantities like length, mass and time. Primary standards are used to calibrate other standards referred to as working standards. [1] [2] See Hierarchy of Standards.
An example of a primary standard was the international prototype of the kilogram (IPK) which was the master kilogram and the primary mass standard for the International System of Units (SI). The IPK is a one kilogram mass of a platinum-iridium alloy maintained by the International Bureau of Weights and Measures (BIPM) in Sèvres, France.
There are three levels of standards in the hierarchy of metrology: primary, secondary, and working standards. [20] Primary standards (the highest quality) do not reference any other standards. Secondary standards are calibrated with reference to a primary standard. Working standards, used to calibrate (or check) measuring instruments or other ...
A standard solution created from a secondary standard cannot have its concentration accurately known without stoichiometric analysis against a primary standard. An example of a secondary standard is sodium hydroxide, a hydroscopic compound that is highly reactive with its surroundings. The concentration of a standard solution made with sodium ...
amount of substance "The mole, symbol mol, is the SI unit of amount of substance. One mole contains exactly 6.022 140 76 × 10 23 elementary entities. This number is the fixed numerical value of the Avogadro constant, N A, when expressed in the unit mol −1 and is called the Avogadro number.
Average time for a particle of a substance to decay s T: intensive Molar concentration: C: Amount of substance per unit volume mol⋅m −3: L −3 N: intensive Molar energy: J/mol: Amount of energy present in a system per unit amount of substance J/mol L 2 M T −2 N −1: intensive Molar entropy: S° Entropy per unit amount of substance J/(K ...
The base units are defined in terms of the defining constants. For example, the kilogram is defined by taking the Planck constant h to be 6.626 070 15 × 10 −34 J⋅s, giving the expression in terms of the defining constants [1]: 131 1 kg = (299 792 458) 2 / (6.626 070 15 × 10 −34)(9 192 631 770) h Δν Cs / c 2 .
The only three verifications occurred in 1889, 1948, and 1989. For instance, the US owns five 90% platinum / 10% iridium (Pt‑10Ir) kilogram standards, two of which, K4 and K20, are from the original batch of 40 replicas distributed in 1884. [Note 4] The K20 prototype was designated as the primary national standard of mass for the US. Both of ...