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The Knudsen number helps determine whether statistical mechanics or the continuum mechanics formulation of fluid dynamics should be used to model a situation. If the Knudsen number is near or greater than one, the mean free path of a molecule is comparable to a length scale of the problem, and the continuum assumption of fluid mechanics is no ...
Knudsen flow describes the movement of fluids with a Knudsen number near unity, that is, where the characteristic length in the flow space is of the same order of magnitude as the mean free path. Depending on the source there is a range mentioned of 0.1<Kn<10 for which Knudsen flow occurs.
The continuum assumption is an idealization of continuum mechanics under which fluids can be treated as continuous, even though, on a microscopic scale, they are composed of molecules. Under the continuum assumption, macroscopic (observed/measurable) properties such as density, pressure, temperature, and bulk velocity are taken to be well ...
Continuum mechanics is a branch of mechanics that deals with the deformation of and transmission of forces through materials modeled as a continuous medium (also called a continuum) rather than as discrete particles. Continuum mechanics deals with deformable bodies, as opposed to rigid bodies. A continuum model assumes that the substance of the ...
In fluid dynamics, the Knudsen equation is used to describe how gas flows through a tube in free molecular flow. When the mean free path of the molecules in the gas is larger than or equal to the diameter of the tube , the molecules will interact more often with the walls of the tube than with each other.
Knudsen diffusion, named after Martin Knudsen, is a means of diffusion that occurs when the scale length of a system is comparable to or smaller than the mean free path of the particles involved. An example of this is in a long pore with a narrow diameter (2–50 nm) because molecules frequently collide with the pore wall. [ 1 ]
By expanding the particle distribution function into equilibrium and non-equilibrium components and using the Chapman-Enskog expansion, where is the Knudsen number, the Taylor-expanded LBE can be decomposed into different magnitudes of order for the Knudsen number in order to obtain the proper continuum equations:
The derivation of Stokes' law, which is used to calculate the drag force on small particles, assumes a no-slip condition which is no longer correct at high Knudsen numbers. The Cunningham slip correction factor allows predicting the drag force on a particle moving a fluid with Knudsen number between the continuum regime and free molecular flow .