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The constant volume adiabatic flame temperature is the temperature that results from a complete combustion process that occurs without any work, heat transfer or changes in kinetic or potential energy. Its temperature is higher than in the constant pressure process because no energy is utilized to change the volume of the system (i.e., generate ...
In thermodynamics, the Volume Correction Factor (VCF), also known as Correction for the effect of Temperature on Liquid (CTL), is a standardized computed factor used to correct for the thermal expansion of fluids, primarily, liquid hydrocarbons at various temperatures and densities. [1]
In all, the higher heating value of hydrogen is 18.2% above its lower heating value (142 MJ/kg vs. 120 MJ/kg). For hydrocarbons, the difference depends on the hydrogen content of the fuel. For gasoline and diesel the higher heating value exceeds the lower heating value by about 10% and 7%, respectively, and for natural gas about 11%.
In gas dynamics we are interested in the local relations between pressure, density and temperature, rather than considering a fixed quantity of gas. By considering the density ρ = M / V {\displaystyle \rho =M/V} as the inverse of the volume for a unit mass, we can take ρ = 1 / V {\displaystyle \rho =1/V} in these relations.
The Wobbe index is expressed in MJ/Nm³ (where 'Nm³' indicates'm³ in Normal conditions), or sometimes in BTU/scf.In the case of natural gas (molar mass 17 g/mol), the typical heating value is around 39 MJ/Nm³ (1,050 BTU/scf) and the specific gravity is approximately 0.59, giving a typical Wobbe index of 51 MJ/Nm³ (1,367 BTU/scf).
However, a common temperature and pressure in use by NIST for thermodynamic experiments is 298.15 K (25 °C, 77 °F) and 1 bar (14.5038 psi, 100 kPa). [4] [5] NIST also uses 15 °C (288.15 K, 59 °F) for the temperature compensation of refined petroleum products, despite noting that these two values are not exactly consistent with each other.
For a gas that is a mixture of two or more pure gases (air or natural gas, for example), the gas composition must be known before compressibility can be calculated. Alternatively, the compressibility factor for specific gases can be read from generalized compressibility charts [ 1 ] that plot Z {\displaystyle Z} as a function of pressure at ...
Flammable gas 462 °C Isobutyl alcohol: 2 11 28 °C Isophorone: 1 4 84 °C Isopropyl alcohol, isopropanol 2 [7] 12 IB 12 °C 398–399 °C; 425 °C [5] Isopropyl chloride: IA Kerosene Jet A-1: 0.6–0.7 4.9–5 II >38 °C, as jet fuel 210 °C Lithium hydride: IA 2-Mercaptoethanol: IIIA Methane (natural gas) ISO10156 5.0 14.3 IA Flammable gas 0. ...