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Mass transfer coefficients can be estimated from many different theoretical equations, correlations, and analogies that are functions of material properties, intensive properties and flow regime (laminar or turbulent flow). Selection of the most applicable model is dependent on the materials and the system, or environment, being studied.
The Sherwood number (Sh) (also called the mass transfer Nusselt number) is a dimensionless number used in mass-transfer operation. It represents the ratio of the total mass transfer rate ( convection + diffusion) to the rate of diffusive mass transport, [ 1 ] and is named in honor of Thomas Kilgore Sherwood .
In convective heat transfer, the Churchill–Bernstein equation is used to estimate the surface averaged Nusselt number for a cylinder in cross flow at various velocities. [1] The need for the equation arises from the inability to solve the Navier–Stokes equations in the turbulent flow regime, even for a Newtonian fluid .
The Nusselt number is the ratio of total heat transfer (convection + conduction) to conductive heat transfer across a boundary. The convection and conduction heat flows are parallel to each other and to the surface normal of the boundary surface, and are all perpendicular to the mean fluid flow in the simple case.
For best accuracy, n should be adjusted where correlations have a different exponent. We can take this further by substituting into this equation the definitions of the heat transfer coefficient, mass transfer coefficient, and Lewis number, yielding: = =
Since the reaction rate determines the reaction timescale, the exact formula for the Damköhler number varies according to the rate law equation. For a general chemical reaction A → B following the Power law kinetics of n-th order , the Damköhler number for a convective flow system is defined as:
In the above equation, four terms represents transience, convection, diffusion and a source term respectively, where T is the temperature in particular case of heat transfer otherwise it is the variable of interest; t is time; c is the specific heat; u is velocity; ε is porosity that is the ratio of liquid volume to the total volume; ρ is ...
The number of transfer units (NTU) method is used to calculate the rate of heat transfer in heat exchangers (especially parallel flow, counter current, and cross-flow exchangers) when there is insufficient information to calculate the log mean temperature difference (LMTD). Alternatively, this method is useful for determining the expected heat ...