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The interest stems from that accurate measurements of the unit cell volume, atomic weight and mass density of a pure crystalline solid provide a direct determination of the Avogadro constant. [ 3 ] The CODATA recommended value for the molar volume of silicon is 1.205 883 199 (60) × 10 −5 m 3 ⋅mol −1 , with a relative standard uncertainty ...
The enthalpy of fusion is the amount of energy required to convert one mole of solid into liquid. For example, when melting 1 kg of ice (at 0 °C under a wide range of pressures), 333.55 kJ of energy is absorbed with no temperature change. The heat of solidification (when a substance changes from liquid to solid) is equal and opposite.
In thermodynamics, the specific volume of a substance (symbol: ν, nu) is the quotient of the substance's volume (V) to its mass (m): = It is a mass-specific intrinsic property of the substance. It is the reciprocal of density ρ and it is also related to the molar volume and molar mass:
Stoichiometry is not only used to balance chemical equations but also used in conversions, i.e., converting from grams to moles using molar mass as the conversion factor, or from grams to milliliters using density. For example, to find the amount of NaCl (sodium chloride) in 2.00 g, one would do the following:
Thus, for example, the average mass of a molecule of water is about 18.0153 daltons, and the molar mass of water is about 18.0153 g/mol. For chemical elements without isolated molecules, such as carbon and metals, the molar mass is computed dividing by the number of moles of atoms instead.
It is a dimensionless quantity with dimension of / and dimensionless unit of moles per mole (mol/mol or mol ⋅ mol-1) or simply 1; metric prefixes may also be used (e.g., nmol/mol for 10-9). [5] When expressed in percent , it is known as the mole percent or molar percentage (unit symbol %, sometimes "mol%", equivalent to cmol/mol for 10 -2 ).
For example, the heat capacity of water ice at the melting point is about 4.6R per mole of molecules, but only 1.5R per mole of atoms. The lower than 3 R number "per atom" (as is the case with diamond and beryllium) results from the “freezing out” of possible vibration modes for light atoms at suitably low temperatures, just as in many low ...
Mass fraction can also be expressed, with a denominator of 100, as percentage by mass (in commercial contexts often called percentage by weight, abbreviated wt.% or % w/w; see mass versus weight). It is one way of expressing the composition of a mixture in a dimensionless size ; mole fraction (percentage by moles , mol%) and volume fraction ...