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Synthetic polymers began replacing other chemical binders for soil stabilization in agriculture in the late 20th century. [1] Compared to traditional chemical binders, polymer soil additives can achieve the same amount of strengthening at much lower concentrations – for example, mixtures of 0.5-1% of various biopolymers have strength levels that match or exceed those of 10% cement mixtures ...
When treated with calcium oxides and water, silicate minerals form Portland cement. Equilibria involving hydrolysis of silicate minerals are difficult to study. The chief challenge is the very low solubility of SiO 4 4-and its various protonated forms. Such equilibria are relevant to the processes occurring on geological time scales.
In the 1950s, Viktor Glukhovsky developed concrete materials originally known as "soil silicate concretes" and "soil cements", [5] but since the introduction of the geopolymer concept by Joseph Davidovits, the terminology and definitions of the word geopolymer have become more diverse and often conflicting.
The carbonate that dissolved is therefore pulled out from the system while the silica precipitated recrystallizes into various silicate minerals, depending on the silica phase. [17] The solubility of silica strongly depends on the temperature and pH value of the environment [ 3 ] where pH9 is the controlling value. [ 1 ]
Siliceous soils are formed from rocks that have silica (SiO 2) as a principal constituent.The parent material of siliceous soils may include quartz sands, chert, quartzite, quartz reefs, granite, rhyolite, ademellite, dellenite, quartz sandstone, quartz siltstone, siliceous tuff, among others. [1]
If the soil particles in a sample are predominantly in a relatively narrow range of sizes, the sample is uniformly graded. If a soil sample has distinct gaps in the gradation curve, e.g., a mixture of gravel and fine sand, with no coarse sand, the sample may be gap graded. Uniformly graded and gap graded soils are both considered to be poorly ...
In polymer chemistry, polymerization (American English), or polymerisation (British English), is a process of reacting monomer molecules together in a chemical reaction to form polymer chains or three-dimensional networks. [1] [2] [3] There are many forms of polymerization [4] and different systems exist to categorize them. IUPAC definition for ...
The subunits of colloidal silica particles are typically in the range of 1 to 5 nm. Whether or not these subunits are joined depends on the conditions of polymerization. Initial acidification of a water-glass (sodium silicate) solution yields Si(OH) 4. If the pH is reduced below 7 or if salt is added, then the units tend to fuse together in chains.