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Lignin plays a crucial part in conducting water and aqueous nutrients in plant stems. The polysaccharide components of plant cell walls are highly hydrophilic and thus permeable to water, whereas lignin is more hydrophobic. The crosslinking of polysaccharides by lignin is an obstacle for water absorption to the cell wall.
Kraft lignin from black liquor, which is produced in much higher amounts, may be processed into sulfonated lignin. The lignin is first precipitated by acidifying the liquor with CO 2 then washed (other methods for isolation exist). Reaction with sodium sulfite or sodium bisulfite and an aldehyde under a basic environment completes sulfonation.
The term "lignin characterization" (or "lignin analysis") refers to a group of activities within lignin research aiming at describing the characteristics of a lignin by determination of its most important properties. [1] Most often, this term is used to describe the characterization of technical lignins by means of chemical or thermo-chemical ...
Guaiacol (/ ˈ ɡ w aɪ ə k ɒ l /) is an organic compound with the formula C 6 H 4 (OH)(OCH 3). It is a phenolic compound containing a methoxy functional group. Guaiacol appears as a viscous colorless oil, although aged or impure samples are often yellowish. It occurs widely in nature and is a common product of the pyrolysis of wood. [3]
An example of a possible lignin structure. The portion shown here (correcting a C 2 H to CH 2 and not counting the side chain denoted "Carbohydrate") has 28 monomers (mostly coniferyl alcohol ), 278 carbon atoms, 407 hydrogen atoms, and 94 oxygen atoms (64% carbon, 8% hydrogen, and 29% oxygen by weight) which seems to be too high in hydrogen.
The black liquor is an aqueous solution of lignin residues, hemicellulose, and the inorganic chemicals used in the process. The black liquor comprises 15% solids by weight of which two thirds are organic chemicals and the remainder are inorganic. [3] Normally the organics in black liquor are 40-45% soaps, [4] 35-45% lignin and 10-15% other ...
It is used to condition soils either by applying it directly to the land, or by providing a source of humic acid or potassium humate for application. The carbon geosequestration potential of Leonardite, particularly to rapidly accelerate microbial action to lock up and retain carbon in soils, provides the basis for extensive research in Victoria on the organic fertilising aspect of brown coal.
In this process lignin and hemicellulose are typically separated from the plant material leaving the fibrous cellulose component to be processed for paper production, or 'chemical cellulose'. [13] Through the pulp process most of the lignin is removed and discharged as waste material in the form of effluent/wastewater before then being used as ...