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Characteristic X-rays are emitted when outer-shell electrons fill a vacancy in the inner shell of an atom, releasing X-rays in a pattern that is "characteristic" to each element. Characteristic X-rays were discovered by Charles Glover Barkla in 1909, [ 1 ] who later won the Nobel Prize in Physics for his discovery in 1917.
The continuous X-spectrum emitted from the tube irradiates the specimen and excites the characteristic spectral X-ray lines in the specimen. Each of the 92 elements emits a characteristic spectrum. Unlike the optical spectrum, the X-ray spectrum is quite simple.
Energy-dispersive X-ray spectroscopy (EDS, EDX, EDXS or XEDS), sometimes called energy dispersive X-ray analysis (EDXA or EDAX) or energy dispersive X-ray microanalysis (EDXMA), is an analytical technique used for the elemental analysis or chemical characterization of a sample. It relies on an interaction of some source of X-ray excitation and ...
Barkla created the x-ray notation for sharp spectral lines, noting in 1909 two separate energies, at first naming them "A" and "B" and then supposing that there may be lines prior to "A", he started an alphabet numbering beginning with "K." [9] [10] Single-slit experiments in the laboratory of Arnold Sommerfeld suggested that X-rays had a ...
Wavelength-dispersive X-ray spectroscopy (WDXS or WDS) is a non-destructive analysis technique used to obtain elemental information about a range of materials by measuring characteristic x-rays within a small wavelength range. The technique generates a spectrum in which the peaks correspond to specific x-ray lines and elements can be easily ...
Ultrafast optical pulses can be used to generate x-ray pulses in multiple ways. An optical pulse can excite an electron pulse via the photoelectric effect, and acceleration across a high potential gives the electrons kinetic energy. When the electrons hit a target they generate both characteristic x-rays and bremsstrahlung. A second method is ...
Moseley's law is an empirical law concerning the characteristic X-rays emitted by atoms. The law had been discovered and published by the English physicist Henry Moseley in 1913–1914. [ 1 ] [ 2 ] Until Moseley's work, "atomic number" was merely an element's place in the periodic table and was not known to be associated with any measurable ...
A Philips PW1606 X-ray fluorescence spectrometer with automated sample feed in a cement plant quality control laboratory XRF scanning of the Rembrandt-painting Syndics of the Drapers' Guild. A Helmut Fischer(company) X-ray fluorescence spectrometer which are used to check for metals coating thickness and any of potential contamination of ...