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There are more complex chemical compounds, the structure of which can only be explained using modern quantum chemical methods, for example, cluster technetium chloride [(CH 3) 4 N] 3 [Tc 6 Cl 14], in which 6 of the 14 chlorine atoms are formally divalent, and oxidation states are fractional.
Chlorine dioxide is a chemical compound with the formula ClO 2 that exists as yellowish-green gas above 11 °C, a reddish-brown liquid between 11 °C and −59 °C, and as bright orange crystals below −59 °C. It is usually handled as an aqueous solution.
The structure of dichlorine monoxide is similar to that of water and hypochlorous acid, with the molecule adopting a bent molecular geometry (due to the lone pairs on the oxygen atom) and resulting in C 2V molecular symmetry. The bond angle is slightly larger than normal, likely due to steric repulsion between the bulky chlorine atoms.
Chlorine oxoacids and structure of dichlorine oxides. Chem. Educator, Vol. 16, 2011, vol. 16, pp. 275—278 This page was last edited on 28 October 2024 ...
Sometimes, this compound is incorrectly named sulfur monochloride (or sulphur monochloride by the British English spelling), the name implied by its empirical formula SCl. S 2 Cl 2 has the structure implied by the formula Cl−S−S−Cl, wherein the dihedral angle between the Cl a −S−S and S−S−Cl b planes is 85.2°.
The structure of sodium chloride, revealing the tendency of chloride ions (green spheres) to link to several cations. The presence of chlorides, such as in seawater, significantly worsens the conditions for pitting corrosion of most metals (including stainless steels, aluminum and high-alloyed materials). Chloride-induced corrosion of steel in ...
Cobalt(II) chloride is an inorganic compound, a salt of cobalt and chlorine, with the formula CoCl 2. The compound forms several hydrates CoCl 2 ·n H 2 O, for n = 1, 2, 6, and 9. Claims of the formation of tri- and tetrahydrates have not been confirmed. [4] The anhydrous form is a blue crystalline solid; the dihydrate is purple and the ...
Dichlorine trioxide, Cl 2 O 3, is a chlorine oxide.It is a dark brown solid discovered in 1967 which is explosive even below 0 °C. [2] It is formed by the low-temperature photolysis of ClO 2 and is formed along with Cl 2 O 6, Cl 2 and O 2.