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Besides the well-known Pitzer-like equations, there is a simple and easy-to-use semi-empirical model, which is called the three-characteristic-parameter correlation (TCPC) model. It was first proposed by Lin et al. [ 22 ] It is a combination of the Pitzer long-range interaction and short-range solvation effect:
In 1923, Peter Debye and Erich Hückel reported the first successful theory for the distribution of charges in ionic solutions. [7] The framework of linearized Debye–Hückel theory subsequently was applied to colloidal dispersions by S. Levine and G. P. Dube [8] [9] who found that charged colloidal particles should experience a strong medium-range repulsion and a weaker long-range attraction.
A stirred BZ reaction mixture showing changes in color over time. The discovery of the phenomenon is credited to Boris Belousov.In 1951, while trying to find the non-organic analog to the Krebs cycle, he noted that in a mix of potassium bromate, cerium(IV) sulfate, malonic acid, and citric acid in dilute sulfuric acid, the ratio of concentration of the cerium(IV) and cerium(III) ions ...
Firstly, equilibrium constants are determined at a number of different ionic strengths, at a chosen temperature and particular background electrolyte. The interaction coefficients are then determined by fitting to the observed equilibrium constant values. The procedure also provides the value of K at infinite dilution. It is not limited to ...
In chemistry, ion association is a chemical reaction whereby ions of opposite electric charge come together in solution to form a distinct chemical entity. [1] [2] Ion associates are classified, according to the number of ions that associate with each other, as ion pairs, ion triplets, etc. Ion pairs are also classified according to the nature of the interaction as contact, solvent-shared or ...
The Debye–Hückel theory was proposed by Peter Debye and Erich Hückel as a theoretical explanation for departures from ideality in solutions of electrolytes and plasmas. [1] It is a linearized Poisson–Boltzmann model, which assumes an extremely simplified model of electrolyte solution but nevertheless gave accurate predictions of mean activity coefficients for ions in dilute solution.
The principle is named after French chemist Henry Louis Le Chatelier who enunciated the principle in 1884 by extending the reasoning from the Van 't Hoff relation of how temperature variations changes the equilibrium to the variations of pressure and what's now called chemical potential, [3] [4] and sometimes also credited to Karl Ferdinand ...
Donnan potential is the difference in the Galvani potentials [1] which appears as a result of Donnan equilibrium, named after Frederick G. Donnan, which refers to the distribution of ion species between two ionic solutions separated by a semipermeable membrane or boundary. [2]