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An antiknock agent is a gasoline additive used to reduce engine knocking and increase the fuel's octane rating by raising the temperature and pressure at which auto-ignition occurs.
In the U.S. MTBE has been used in gasoline at low levels since 1979, replacing tetraethyllead (TEL) as an antiknock (octane rating) additive to prevent engine knocking. [19] Oxygenates also help gasoline burn more completely, reducing tailpipe emissions. Oxygenates also dilute or displace gasoline components such as aromatics (e.g., benzene ...
The octane rating of gasoline is measured in a test engine and is defined by comparison with the mixture of 2,2,4-trimethylpentane (iso-octane) and normal heptane that would have the same anti-knocking capability as the fuel under test. The percentage, by volume, of 2,2,4-trimethylpentane in that mixture is the octane number of the fuel.
Fuel additives in the United States are regulated under section 211 of the Clean Air Act (as amended in January 1995). The Environmental Protection Agency (EPA) requires the registration of all fuel additives which are commercially distributed for use in highway motor vehicles in the United States, [8] and may require testing and ban harmful additives.
A gasoline-fuelled reciprocating engine requires fuel of sufficient octane rating to prevent uncontrolled combustion (preignition and detonation). [9] Antiknock agents allow the use of higher compression ratios for greater efficiency [22] and peak power. [23]
Methylcyclopentadienyl manganese tricarbonyl (MMT or MCMT) is an organomanganese compound with the formula (C 5 H 4 CH 3)Mn(CO) 3.Initially marketed as a supplement for use in leaded gasoline, MMT was later used in unleaded gasoline to increase the octane rating.
Modern knock control-loop systems are able to adjust ignition timings for every cylinder individually. Depending on the specific engine the boost pressure is regulated simultaneously. This way performance is kept at its optimum while mostly eliminating the risk of engine damage caused by knock (e.g. when running on low octane fuel). [5]
N-Methylaniline is a principal component of NMA (monomethylaniline), a non-traditional antiknock agent increasingly used by petroleum refiners and fuel distributors around the world to increase the octane number of gasoline petrol.
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