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The PUREX process was invented by Herbert H. Anderson and Larned B. Asprey at the Metallurgical Laboratory at the University of Chicago, as part of the Manhattan Project under Glenn T. Seaborg; their patent "Solvent Extraction Process for Plutonium" filed in 1947, [14] mentions tributyl phosphate as the major reactant which accomplishes the ...
PUREX, the current standard method, is an acronym standing for Plutonium and Uranium Recovery by EXtraction. The PUREX process is a liquid-liquid extraction method used to reprocess spent nuclear fuel, to extract uranium and plutonium, independent of each other, from the fission products. This is the most developed and widely used process in ...
REDOX, PUREX: Shut down 1944 1988 Military Savannah River Site: South Carolina: LWR PUREX: Shut down 5000 1952 2002 Civil West Valley LWR PUREX: Shut down 300 1966 1972 Civil Barnwell LWR Finished; never entered service 1500 INL LWR Shut down Morris Operation: Morris, Illinois: Construction halted; never entered service, completion proposed ...
The first reprocessing approach is based on the PUREX (Plutonium Uranium Reduction EXtraction) process, which is the standard and mature technology applied worldwide to recover uranium and plutonium from spent nuclear fuel at industrial scale. Following the dissolution of the spent fuel in nitric acid and the removal of uranium and plutonium ...
The UREX process is a PUREX process which has been modified to prevent the plutonium being extracted. This can be done by adding a plutonium reductant before the first metal extraction step. In the UREX process, ~99.9% of the uranium and >95% of technetium are separated from each other and the other fission products and actinides. The key is ...
It is also used in nuclear reprocessing as part of the PUREX process. A 15–40% (usually about 30%) solution of tributyl phosphate in kerosene or dodecane is used in the liquid–liquid extraction (solvent extraction) of uranium, plutonium, and thorium from spent uranium nuclear fuel rods dissolved in nitric acid. Liquid extraction can also be ...
During reprocessing activities, some of the feed for the second cycle (medium active part) of the PUREX process escaped in an accident involving red oil. According to the IAEA it was estimated that the following isotopes were released from the reaction vessel: [6] Normalized to the same first day dose rate. (logarithmic scale). 106 Ru 7.9 TBq ...
It is possible, however, to remove the americium from the plutonium by a chemical separation process. Even under the worst conditions, the americium/plutonium mixture is less radioactive than a spent-fuel dissolution liquor, so it should be relatively straightforward to recover the plutonium by PUREX or another aqueous reprocessing method.