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Semi-stable metal complexes can be used to produce sub-2 nm oxide particles without thermal treatment. During base-catalyzed synthesis, hydroxo (M-OH) bonds may be avoided in favor of oxo (M-O-M) using a ligand which is strong enough to prevent reaction in the hydroxo regime but weak enough to allow reaction in the oxo regime (see Pourbaix ...
A solid oxide electrolyser cell (SOEC) is a solid oxide fuel cell set in regenerative mode for the electrolysis of water with a solid oxide, or ceramic, electrolyte to produce oxygen and hydrogen gas. [53] SOECs can also be used to do electrolysis of CO 2 to produce CO and oxygen [54] or even co-electrolysis of water and CO 2 to produce syngas ...
Schematic illustration of one reaction cycle of the ALD process, using the trimethylaluminium (TMA) -water process to make thin aluminium oxide films as (simplified) example. There, the starting surface contains hydroxyls (OH groups) as reactive sites; Step 1 is the reaction of TMA; Step 2 is a purge or evacuation step, Step 3 is the reaction ...
In the temperature ranges commonly used, the metal and the oxide are in a condensed state (solid or liquid), and oxygen is a gas with a much larger molar entropy. For the oxidation of each metal, the dominant contribution to the entropy change (ΔS) is the removal of 1 ⁄ 2 mol O 2, so that ΔS is negative and roughly equal for all metals.
These catalysts initiate radical chain reactions, autoxidation that produce organic radicals that combine with oxygen to give hydroperoxide intermediates. Generally the selectivity of oxidation is determined by bond energies. For example, benzylic C-H bonds are replaced by oxygen faster than aromatic C-H bonds. [2]
A large molecule with an ionized group is technically an ion, but its behavior may be largely the result of non-ionic interactions. For example, sodium stearate (the main constituent of traditional soaps) consists entirely of ions, yet it is a soft material quite unlike a typical ionic solid. There is a continuum between ionic solids and ...
For some metals, carbothermic reactions do not afford the metal, but instead give the metal carbide. This behavior is observed for titanium, hence the use of the chloride process. Carbides also form upon high temperature treatment of Cr 2 O 3 with carbon. For this reason, aluminium is employed as the reducing agent.
In August 1942 the lab's chemical section was the first to chemically separate a weighable sample of plutonium, and on 2 December 1942, the Met Lab produced the first controlled nuclear chain reaction, in the reactor Chicago Pile-1, which was constructed under the stands of the university's old football stadium, Stagg Field.