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  2. Tetrahedral molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Tetrahedral_molecular_geometry

    In a tetrahedral molecular geometry, a central atom is located at the center with four substituents that are located at the corners of a tetrahedron. The bond angles are arccos (− ⁠ 1 / 3 ⁠ ) = 109.4712206...° ≈ 109.5° when all four substituents are the same, as in methane ( CH 4 ) [ 1 ] [ 2 ] as well as its heavier analogues .

  3. Molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Molecular_geometry

    Molecular geometry is the three-dimensional arrangement of the atoms that constitute a molecule. It includes the general shape of the molecule as well as bond lengths , bond angles , torsional angles and any other geometrical parameters that determine the position of each atom.

  4. Tetrahedron - Wikipedia

    en.wikipedia.org/wiki/Tetrahedron

    The isometries of an irregular (unmarked) tetrahedron depend on the geometry of the tetrahedron, with 7 cases possible. In each case a 3-dimensional point group is formed. Two other isometries (C 3, [3] +), and (S 4, [2 +,4 +]) can exist if the face or edge marking are included. Tetrahedral diagrams are included for each type below, with edges ...

  5. VSEPR theory - Wikipedia

    en.wikipedia.org/wiki/VSEPR_theory

    In contrast, the extra stability of the 7p 1/2 electrons in tennessine are predicted to make TsF 3 trigonal planar, unlike the T-shaped geometry observed for IF 3 and predicted for AtF 3; [39] similarly, OgF 4 should have a tetrahedral geometry, while XeF 4 has a square planar geometry and RnF 4 is predicted to have the same. [40]

  6. Chirality (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Chirality_(chemistry)

    Chiral molecules will usually have a stereogenic element from which chirality arises. The most common type of stereogenic element is a stereogenic center, or stereocenter. In the case of organic compounds, stereocenters most frequently take the form of a carbon atom with four distinct (different) groups attached to it in a tetrahedral geometry.

  7. Bent's rule - Wikipedia

    en.wikipedia.org/wiki/Bent's_rule

    Shape of water molecule showing that the real bond angle 104.5° deviates from the ideal sp 3 angle of 109.5°. In chemistry, Bent's rule describes and explains the relationship between the orbital hybridization and the electronegativities of substituents. [1] [2] The rule was stated by Henry A. Bent as follows: [2]

  8. T-shaped molecular geometry - Wikipedia

    en.wikipedia.org/wiki/T-shaped_molecular_geometry

    Although this anion has been detected in the gas phase, attempts at synthesis in solution and experimental structure determination were unsuccessful. A computational chemistry study showed a distorted planar Y-shaped geometry with the smallest F–Xe–F bond angle equal to 69°, rather than 90° as in a T-shaped geometry. [3]

  9. Geometry index - Wikipedia

    en.wikipedia.org/wiki/Geometry_index

    In coordination chemistry and crystallography, the geometry index or structural parameter (τ) is a number ranging from 0 to 1 that indicates what the geometry of the coordination center is. The first such parameter for 5-coordinate compounds was developed in 1984. [ 1 ]