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Polyaspartic ester chemistry was first introduced in the early 1990s making it a relatively new technology. [1] [2] [3] The patents were issued to Bayer in Germany and Miles Corporation in the United States. It utilizes the aza-Michael addition reaction. [4] [5] These products are then used in coatings, adhesives, sealants and elastomers. [6]
Due to presence of carboxylic groups it is polyelectrolyte with anionic character. Naturally occurring PASA fragments consists of α,-linked L-aspartatic acid. [5] In contrast, the repeating unit of synthetic polyaspartic acid may exist in four isomeric forms, depending on the stereochemistry of starting material (D- and L-aspartic acid) and synthetic procedure leading to α and β links.
The phosphoric acid is washed out and the dried polysuccinimide is converted by mild alkaline hydrolysis into water-soluble polyaspartic acid; the molar mass of which can be determined by gel permeation chromatography. The process provides reproducible polysuccinimide with molar masses above 100,000 g/mol.
A polyamine is an organic compound having more than two amino groups.Alkyl polyamines occur naturally, but some are synthetic. Alkylpolyamines are colorless, hygroscopic, and water soluble.
A Assuming an altitude of 194 metres above mean sea level (the worldwide median altitude of human habitation), an indoor temperature of 23 °C, a dewpoint of 9 °C (40.85% relative humidity), and 760 mmHg sea level–corrected barometric pressure (molar water vapor content = 1.16%).
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