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In chemistry, the mass concentration ρ i (or γ i) is defined as the mass of a constituent m i divided by the volume of the mixture V. [1]= For a pure chemical the mass concentration equals its density (mass divided by volume); thus the mass concentration of a component in a mixture can be called the density of a component in a mixture.
where is the viscosity of the liquid mixture, is the viscosity (equation) for fluid component i when flowing as a pure fluid, and is the molfraction of component i in the liquid mixture. The Grunberg-Nissan (1949) [ 10 ] mixing rule extends the Arrhenius rule to
This type of mixture, being a finite sum, is called a finite mixture, and in applications, an unqualified reference to a "mixture density" usually means a finite mixture. The case of a countably infinite set of components is covered formally by allowing n = ∞ {\displaystyle n=\infty \!} .
Because the individual masses of the ingredients of a mixture sum to , their mass fractions sum to unity: ∑ i = 1 n w i = 1. {\displaystyle \sum _{i=1}^{n}w_{i}=1.} Mass fraction can also be expressed, with a denominator of 100, as percentage by mass (in commercial contexts often called percentage by weight , abbreviated wt.% or % w/w ; see ...
The volume of such a mixture is slightly less than the sum of the volumes of the components. Thus, by the above definition, the term "40% alcohol by volume" refers to a mixture of 40 volume units of ethanol with enough water to make a final volume of 100 units, rather than a mixture of 40 units of ethanol with 60 units of water.
Density (volumetric mass density or specific mass) is a substance's mass per unit of volume.The symbol most often used for density is ρ (the lower case Greek letter rho), although the Latin letter D can also be used.
The ideal gas equation can be rearranged to give an expression for the molar volume of an ideal gas: = = Hence, for a given temperature and pressure, the molar volume is the same for all ideal gases and is based on the gas constant: R = 8.314 462 618 153 24 m 3 ⋅Pa⋅K −1 ⋅mol −1, or about 8.205 736 608 095 96 × 10 −5 m 3 ⋅atm⋅K ...
The equation can only be applied when the purged volume of vapor or gas is replaced with "clean" air or gas. For example, the equation can be used to calculate the time required at a certain ventilation rate to reduce a high carbon monoxide concentration in a room.
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