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Woodward's rules, named after Robert Burns Woodward and also known as Woodward–Fieser rules (for Louis Fieser) are several sets of empirically derived rules which attempt to predict the wavelength of the absorption maximum (λ max) in an ultraviolet–visible spectrum of a given compound.
The vibrational and rotational excited states of greenhouse gases that emit thermal infrared radiation are in LTE up to about 60 km. [7] Radiative transfer calculations show negligible change (0.2%) due to absorption and emission above about 50 km. Schwarzschild's equation therefore is appropriate for most problems involving thermal infrared in ...
In 1890, Rydberg proposed on a formula describing the relation between the wavelengths in spectral lines of alkali metals. [2]: v1:376 He noticed that lines came in series and he found that he could simplify his calculations using the wavenumber (the number of waves occupying the unit length, equal to 1/λ, the inverse of the wavelength) as his unit of measurement.
Formally, the wavelength version of Wien's displacement law states that the spectral radiance of black-body radiation per unit wavelength, peaks at the wavelength given by: = where T is the absolute temperature and b is a constant of proportionality called Wien's displacement constant, equal to 2.897 771 955... × 10 −3 m⋅K, [1] [2] or b ...
A corollary of Kasha's rule is the Vavilov rule, which states that the quantum yield of luminescence is generally independent of the excitation wavelength. [4] [7] This can be understood as a consequence of the tendency – implied by Kasha's rule – for molecules in upper states to relax to the lowest excited state non-radiatively.
The wavelength (or equivalently, frequency) of the photon is determined by the difference in energy between the two states. These emitted photons form the element's spectrum. The fact that only certain colors appear in an element's atomic emission spectrum means that only certain frequencies of light are emitted.
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