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The Bunsen reaction is a chemical reaction that describes water, sulfur dioxide, and iodine reacting to form sulfuric acid and hydrogen iodide: 2H 2 O + SO 2 + I 2 → H 2 SO 4 + 2HI This reaction is the first step in the sulfur-iodine cycle to produce hydrogen .
Sulfur dioxide is fairly soluble in water, and by both IR and Raman spectroscopy; the hypothetical sulfurous acid, H 2 SO 3, is not present to any extent. However, such solutions do show spectra of the hydrogen sulfite ion, HSO 3 −, by reaction with water, and it is in fact the actual reducing agent present: SO 2 + H 2 O ⇌ HSO 3 − + H +
The contact process is a method of producing sulfuric acid in the high concentrations needed for industrial processes. Platinum was originally used as the catalyst for this reaction; however, because it is susceptible to reacting with arsenic impurities in the sulfur feedstock, vanadium(V) oxide (V 2 O 5) has since been preferred.
This is illustrated in the image here, where the balanced equation is: CH 4 + 2 O 2 → CO 2 + 2 H 2 O. Here, one molecule of methane reacts with two molecules of oxygen gas to yield one molecule of carbon dioxide and two molecules of water. This particular chemical equation is an example of complete combustion. Stoichiometry measures these ...
Water: Gas H 2 O −241.818 Water: Liquid H 2 O −285.8 Hydrogen ion: Aqueous H + 0 Hydroxide ion: Aqueous OH −: −230 Hydrogen peroxide: Liquid H 2 O 2: −187.8 Phosphoric acid: Liquid H 3 PO 4: −1288 Hydrogen cyanide: Gas HCN 130.5 Hydrogen bromide: Liquid HBr −36.3 Hydrogen chloride: Gas HCl −92.30 Hydrogen chloride: Aqueous HCl ...
They can also be described by the formula H 2 SO 4 ·xSO 3 where x is now defined as the molar free sulfur trioxide content. Oleum is generally assessed according to the free SO 3 content by mass. It can also be expressed as a percentage of sulfuric acid strength; for oleum concentrations, that would be over 100%.
The water, SO 2 and residual H 2 SO 4 must be separated from the oxygen byproduct by condensation. 2 HI I 2 + H 2 (450 °C (840 °F)) Iodine and any accompanying water or SO 2 are separated by condensation, and the hydrogen product remains as a gas. Net reaction: 2 H 2 O → 2 H 2 + O 2
Treatment of sulfur with hydrogen gives hydrogen sulfide.When dissolved in water, hydrogen sulfide is mildly acidic: [5] H 2 S ⇌ HS − + H +. Hydrogen sulfide gas and the hydrosulfide anion are extremely toxic to mammals, due to their inhibition of the oxygen-carrying capacity of hemoglobin and certain cytochromes in a manner analogous to cyanide and azide.