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A 1,2-rearrangement is an organic reaction where a substituent moves from one atom to another atom in a chemical compound. In a 1,2 shift the movement involves two adjacent atoms but moves over larger distances are possible. Skeletal isomerization is not normally encountered in the laboratory, but is the basis of large applications in oil ...
Corey–Winter reaction; Cornforth rearrangement; Coupling reaction; Crabbé reaction; Craig method; Cram's rule of asymmetric induction; Creighton process; Criegee reaction; Criegee rearrangement; Cross metathesis; Crum Brown–Gibson rule; Curtius degradation; Curtius rearrangement, Curtius reaction; Cyanohydrin reaction
Organic reactions can be categorized based on the type of functional group involved in the reaction as a reactant and the functional group that is formed as a result of this reaction. For example, in the Fries rearrangement the reactant is an ester and the reaction product an alcohol .
The Carroll rearrangement is a rearrangement reaction in organic chemistry and involves the transformation of a β-keto allyl ester into a α-allyl-β-ketocarboxylic acid. [18] This organic reaction is accompanied by decarboxylation and the final product is a γ,δ-allylketone.
The Hofmann rearrangement (Hofmann degradation) is the organic reaction of a primary amide to a primary amine with one less carbon atom. [1] [2] [3] The reaction involves oxidation of the nitrogen followed by rearrangement of the carbonyl and nitrogen to give an isocyanate intermediate.
The Stevens rearrangement in organic chemistry is an organic reaction converting quaternary ammonium salts and sulfonium salts to the corresponding amines or sulfides in presence of a strong base in a 1,2-rearrangement. [1] Stevens rearrangement overview. The reactants can be obtained by alkylation of the corresponding amines and sulfides.
The organic group "R2" shown in the diagram above on the bottom right is the methyl violet carbocation, whose pK R+ of 9.4 is not sufficient to out-compete loss of H + and therefore a classical Pummerer rearrangement occurs. The reaction on the left is a fragmentation because the leaving group with pK R+ = 23.7 is particularly stable.
The benzilic acid rearrangement is formally the 1,2-rearrangement of 1,2-diketones to form α-hydroxy–carboxylic acids using a base. This reaction receives its name from the reaction of benzil with potassium hydroxide to form benzilic acid. First performed by Justus von Liebig in 1838, [1] it is the first reported example of a rearrangement ...