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Hydration reaction mechanism from 1-methylcyclohexene to 1-methylcyclohexanol. Many alternative routes are available for producing alcohols, including the hydroboration–oxidation reaction , the oxymercuration–reduction reaction , the Mukaiyama hydration , the reduction of ketones and aldehydes and as a biological method fermentation .
[1] [2] [3] It can also be synthesized as a side product of the dehydration of 2-methylcyclohexanol into 1-methylcyclohexene. Structure
4-Methylcyclohexene is an organic compound consisting of cyclohexene with a methyl group substituent attached to carbon most distant from the alkene group. Two other structural isomers are known: 1-methylcyclohexene and 3-methylcyclohexene. All are colorless volatile liquids classified as a cyclic olefins. They are specialized reagents.
Professor David Todd at Pomona College was testing the dehydration of 2-methylcyclohexanol or 4-methylcyclohexanol c. 1994 and unexpectedly interrupted the alkene distillation midway to have lunch with his secretary, Evelyn Jacoby. After lunch, he continued his distillation but kept the early products separate from the completed ones.
Methylcyclohexene can refer to any of three compounds: 1-Methylcyclohexene; 3-Methylcyclohexene; 4-Methylcyclohexene This page was last edited on 18 November ...
Oxidation of 1-methylcyclohexene catalyzed by cytochrome P450 yields a 2:1 mixture of hydroxylation to epoxidation products. [4] The stereochemistry of hydroformylation has been examined using 1-methylcyclohexene. The main product has the formyl group on the less substituted alkene-carbon, trans with respect to the methyl substituent.
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Oxymercuration reaction [1] In organic chemistry , the oxymercuration reaction is an electrophilic addition reaction that transforms an alkene ( R 2 C=CR 2 ) into a neutral alcohol . In oxymercuration, the alkene reacts with mercuric acetate ( AcO−Hg−OAc ) in aqueous solution to yield the addition of an acetoxymercury ( −HgOAc ) group and ...