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The ultimate strength of concrete is influenced by the water-cementitious ratio (w/cm), the design constituents, and the mixing, placement and curing methods employed.All things being equal, concrete with a lower water-cement (cementitious) ratio makes a stronger concrete than that with a higher ratio. [2]
The ratio Ca/Si (C/S) and Mg/Si (M/S) decrease from 2 for the dicalcium and dimagnesium silicate reagents to 1.5 for the hydrated silicate products of the hydration reaction. In other term, the C-S-H or the serpentine are less rich in Ca and Mg respectively.
A higher ratio gives a too fluid concrete mix resulting in a too porous hardened concrete of poor quality. Often, the concept also refers to the ratio of water to cementitious materials, w/cm. Cementitious materials include cement and supplementary cementitious materials such as ground granulated blast-furnace slag (GGBFS), fly ash (FA), silica ...
Cement hydration and strength development mainly depend on two silicate phases: tricalcium silicate (C 3 S) (), and dicalcium silicate (C 2 S) (). [1] Upon hydration, the main reaction products are calcium silicate hydrates (C-S-H) and calcium hydroxide Ca(OH) 2, written as CH in the cement chemist notation.
Synthetic C-S-H can be divided in two categories separated at the Ca/Si ratio of about 1.1. There are several indications that the chemical, physical and mechanical characteristics of C-S-H varies noticeably between these two categories.
In industry, the various grades of sodium silicate are characterized by their SiO 2:Na 2 O weight ratio (which can be converted to molar ratio by multiplication with 1.032). The ratio can vary between 1:2 and 3.75:1. [1] Grades with ratio below 2.85:1 are termed alkaline. Those with a higher SiO 2:Na 2 O ratio are described as neutral.
Instead of using a 'nominal mix' of 1 part cement, 2 parts sand, and 4 parts aggregate, a civil engineer will custom-design a concrete mix to exactly meet the requirements of the site and conditions, setting material ratios and often designing an admixture package to fine-tune the properties or increase the performance envelope of the mix ...
2.2 Solvent mixtures mixing ratios. ... the dimensionless mixing ratio is the abundance of one component of a mixture relative to that of all other components.