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The production of butanol by biological means was first performed by Louis Pasteur in 1861. [5] In 1905, Austrian biochemist Franz Schardinger found that acetone could similarly be produced. [5] In 1910 Auguste Fernbach (1860–1939) developed a bacterial fermentation process using potato starch as a feedstock in the production of butanol. [6]
A senior lecturer at the University of Manchester, England, he used them in 1916 as a bio-chemical tool to produce at the same time, jointly, acetone, ethanol, and n-butanol from starch. The method has been described since as the ABE process , (Acetone Butanol Ethanol fermentation process), yielding 3 parts of acetone , 6 of n -butanol, and 1 ...
In ethanol fermentation, one glucose molecule is converted into two ethanol molecules and two carbon dioxide (CO 2) molecules. [11] [12] It is used to make bread dough rise: the carbon dioxide forms bubbles, expanding the dough into a foam. [13] [14] The ethanol is the intoxicating agent in alcoholic beverages such as wine, beer and liquor. [15]
Solvents used include acetone, methanol, ethanol, butanol, ethylene glycol, formic acid, and acetic acid. The concentration of solvent in water ranges from 40 to 80%. Higher boiling solvents have the advantage of a lower process pressure. This is weighed against the more difficult solvent recovery by distillation. [2]
Fermentation is a biochemical process during which yeast and certain bacteria convert sugars to ethanol, carbon dioxide, as well as other metabolic byproducts. [ 73 ] [ 74 ] The average human digestive system produces approximately 3 g of ethanol per day through fermentation of its contents. [ 75 ]
The dominant ethanol feedstock in warmer regions is sugarcane. [8] In temperate regions, corn or sugar beets are used. [8] [9] In the United States, the main feedstock for the production of ethanol is currently corn. [8] Approximately 2.8 gallons of ethanol are produced from one bushel of corn (0.42 liter per kilogram).
Butanol (also called butyl alcohol) is a four-carbon alcohol with a formula of C 4 H 9 O H, which occurs in five isomeric structures (four structural isomers), from a straight-chain primary alcohol to a branched-chain tertiary alcohol; [1] all are a butyl or isobutyl group linked to a hydroxyl group (sometimes represented as BuOH, sec-BuOH, i-BuOH, and t-BuOH).
The production of acetone by acetoacetate decarboxylase-containing or clostridial bacteria was utilized in large-scale industrial syntheses in the first half of the twentieth century. In the 1960s, the industry replaced this process with less expensive, more efficient chemical syntheses of acetone from petroleum and petroleum derivatives. [6]