Search results
Results from the WOW.Com Content Network
In outer sphere redox reactions no bonds are formed or broken; only an electron transfer (ET) takes place. A quite simple example is the Fe 2+ /Fe 3+ redox reaction, the self exchange reaction which is known to be always occurring in an aqueous solution containing the aquo complexes [Fe(H 2 O) 6] 2+ and [Fe(H 2 O)6] 3+.
In heterogeneous electron transfer, an electron moves between a chemical species present in solution and the surface of a solid such as a semi-conducting material or an electrode. Theories addressing heterogeneous electron transfer have applications in electrochemistry and the design of solar cells.
The Monte Carlo method for electron transport is a semiclassical Monte Carlo (MC) approach of modeling semiconductor transport. Assuming the carrier motion consists of free flights interrupted by scattering mechanisms, a computer is utilized to simulate the trajectories of particles as they move across the device under the influence of an electric field using classical mechanics.
Electron-transfer theories describe the influence of a variety of parameters on the rate of electron-transfer. All electrochemical reactions occur by this mechanism. Adiabatic electron-transfer theory stresses that intricately coupled to such charge transfer is the ability of any D-A system to absorb or emit light.
Electrochemical kinetics is the field of electrochemistry that studies the rate of electrochemical processes. This includes the study of how process conditions, such as concentration and electric potential, influence the rate of oxidation and reduction reactions that occur at the surface of an electrode, as well as an investigation into electrochemical reaction mechanisms.
This theory has largely been disproven by FT electron spectroscopy experiments that show electron absorption and transfer with an efficiency of above 99%, [61] which cannot be explained by classical mechanical models. Instead, as early as 1938, scientists theorized that quantum coherence was the mechanism for excitation-energy transfer.
Characterization of transport properties requires fabricating a device and measuring its current-voltage characteristics. Devices for transport studies are typically fabricated by thin film deposition or break junctions. The dominant transport mechanism in a measured device can be determined by differential conductance analysis.
The electron transfer between the reactant and the nanoelectrode can be explained by the combination of various theories based on the Marcus theory. Mass transport, that is the diffusion of the reactant molecules from the electrolyte bulk to the nanoelectrode, is influenced by the formation of a double electric layer at the electrode ...